• 1350 Citations
  • 21 h-Index
19972019
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Research Output 1997 2019

2019
2 Citations (Scopus)
Lipopolysaccharides
Nitric Oxide
Acylation
Hydroxylation
Butyrates
Biological Products
Lipase
Hydrolysis
Esters
Candida antarctica lipase B

Site-selective synthesis of acacetin and genkwanin through lipase-catalyzed deacetylation of apigenin 5,7-diacetate and subsequent methylation

Fujita, R., Mandal, S., Hanaya, K., Shoji, M., Higashibayashi, S. & Sugai, T., 2019 Jan 1, In : Heterocycles. 99, 1, p. 638-648 11 p.

Research output: Contribution to journalArticle

Apigenin
Methylation
Lipase
Ions
Porifera
2018
4 Citations (Scopus)

Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries

Shimizu, T., Yamamoto, K., Pandit, P., Yoshikawa, H. & Higashibayashi, S., 2018 Dec 1, In : Scientific Reports. 8, 1, 579.

Research output: Contribution to journalArticle

hydrazine
Heterocyclic Compounds
Lithium
Cathodes
Electrodes
1 Citation (Scopus)

Chemoenzymatic approaches to the synthesis of the (1S,2R)-isomer of benzyl 2-hydroxycyclohexanecarboxylate

Tsunekawa, R., Hanaya, K., Higashibayashi, S., Shoji, M. & Sugai, T., 2018 Jan 1, In : Molecular Catalysis. 444, p. 84-89 6 p.

Research output: Contribution to journalArticle

Isomers
isomers
synthesis
Stereoisomerism
enzymes

Dearomative Oxidative Rearrangement of [3]Cyclo-1,8-carbazolylene

Yasui, M., Ohtsu, H., Kawano, M., Hanaya, K., Sugai, T. & Higashibayashi, S., 2018 Jan 1, In : Chemistry Letters. 47, 11, p. 1357-1359 3 p.

Research output: Contribution to journalArticle

Derivatives
X ray analysis
Ultraviolet spectroscopy
Absorption spectroscopy
Discrete Fourier transforms
2 Citations (Scopus)

Formal total synthesis of (-)-hamigeran B from a chemo-enzymatically prepared building block with quaternary chiral center

Kuwata, K., Fujita, R., Hanaya, K., Higashibayashi, S. & Sugai, T., 2018 Jan 1, (Accepted/In press) In : Tetrahedron.

Research output: Contribution to journalArticle

Hydrogenation
Alcohol Oxidoreductases
Stereochemistry
Cyclization
Catalysis
1 Citation (Scopus)

Molecular Arrangements of Corannulene and Sumanene in Single-Walled Carbon Nanotubes

Iizumi, Y., Liu, Z., Suenaga, K., Okada, S., Higashibayashi, S., Sakurai, H. & Okazaki, T., 2018 Jan 1, (Accepted/In press) In : ChemNanoMat.

Research output: Contribution to journalArticle

Single-walled carbon nanotubes (SWCN)
Photoluminescence spectroscopy
Molecular orientation
Infrared spectroscopy
Microscopic examination
4 Citations (Scopus)
Biological Products
Alcohols
Availability
Enantiomers
Chirality
hydrazine
Sulfoxides
Heterocyclic Compounds
sulfoxide
Fluorescence
Aldehydes
Steroids
Lewis Acids
Bromides
Lithium
Drug Resistance
Protein Binding
Adenosine Triphosphate
irinotecan
Breast Neoplasms
3 Citations (Scopus)
Quercetin
Molecules
fisetin
naringin
3 Citations (Scopus)

Synthesis of flake-shaped [3]cyclo-4,6-dibenzofuranylene

Higashibayashi, S., 2018 Jan 1, In : Chemistry Letters. 47, 1, p. 95-96 2 p.

Research output: Contribution to journalArticle

Propellers
Discrete Fourier transforms
dibenzofuran
cyclo 3
4 Citations (Scopus)

Synthesis of oroxylin A starting from naturally abundant baicalin

Fujita, R., Hanaya, K., Higashibayashi, S. & Sugai, T., 2018 Jan 1, In : Heterocycles. 97, 2, p. 1165-1174 10 p.

Research output: Contribution to journalArticle

Ether
Sterilizers
Acetylation
Methylation
Glucuronides
2 Citations (Scopus)
Hydrolysis
Sterilizers
2,4-Dichlorophenoxyacetic Acid
Steam
Pressure
7 Citations (Scopus)

Triazasumanene: An isoelectronic heteroanalogue of sumanene

Tan, Q., Kaewmati, P., Higashibayashi, S., Kawano, M., Yakiyama, Y. & Sakurai, H., 2018 Jan 1, In : Bulletin of the Chemical Society of Japan. 91, 4, p. 531-537 7 p.

Research output: Contribution to journalArticle

Crystals
Chirality
Optical band gaps
Molecular orbitals
Electronic structure
10 Citations (Scopus)

Tris(2-hydroxyphenyl)triazasumanene: Bowl-shaped excited-state intramolecular proton transfer (ESIPT) fluorophore coupled with aggregation-induced enhanced emission (AIEE)

Kaewmati, P., Yakiyama, Y., Ohtsu, H., Kawano, M., Haesuwannakij, S., Higashibayashi, S. & Sakurai, H., 2018 Jan 1, In : Materials Chemistry Frontiers. 2, 3, p. 514-519 6 p.

Research output: Contribution to journalArticle

Proton transfer
Fluorophores
Excited states
Agglomeration
Single crystals
2017

Construction of 2,6,9,11-tetraoxatricyclo[6.2.1.03,8]undecane containing 4-keto-D-glucose skeleton

Fujitani, B., Hanaya, K., Higashibayashi, S., Shoji, M. & Sugai, T., 2017 Dec 21, In : Tetrahedron. 73, 51, p. 7217-7222 6 p.

Research output: Contribution to journalArticle

Spironolactone
Stereochemistry
Skeleton
Scaffolds
undecane
4 Citations (Scopus)

Electronic and vibrational structures in the S0 and S1 states of coronene

Kunishige, S., Kanaoka, A., Katori, T., Kawabata, M., Baba, M., Yamanaka, T., Higashibayashi, S. & Sakurai, H., 2017 Jan 28, In : Journal of Chemical Physics. 146, 4, 044309.

Research output: Contribution to journalArticle

electronic structure
Fluorescence
Molecular structure
fluorescence
Benzene
3 Citations (Scopus)

Non-Planar [n]Cyclo-1,8-carbazolylenes (n=3,4,6) and [3]Cyclo-1,8-carbazolylenyl B, P, PO, SiPh Complexes

Yamamoto, K., Pandit, P. & Higashibayashi, S., 2017 Oct 9, In : Chemistry - A European Journal. 23, 56, p. 14011-14016 6 p.

Research output: Contribution to journalArticle

Oligomerization
Polysilicon
Acidity
Electronic structure
Boron
4 Citations (Scopus)

Sumanene derivatives functionalized at the internal carbon

Ngamsomprasert, N., Dang, J. S., Higashibayashi, S., Yakiyama, Y. & Sakurai, H., 2017, In : Chemical Communications. 53, 4, p. 697-700 4 p.

Research output: Contribution to journalArticle

Enantiomers
Carbon
Derivatives
X rays
Crystals
3 Citations (Scopus)

Synthesis of a C70 Fragment Buckybowl C28H14 from a C60 fragment sumanene

Hishikawa, S., Okabe, Y., Tsuruoka, R., Higashibayashi, S., Ohtsu, H., Kawano, M., Yakiyama, Y. & Sakurai, H., 2017, In : Chemistry Letters. 46, 10, p. 1556-1559 4 p.

Research output: Contribution to journalArticle

Physical properties
sumanene
3 Citations (Scopus)
Diterpenes
Skeleton
Molecules
cotylenin A
cyclopentanone
11 Citations (Scopus)

Synthesis of triaryltriazasumanenes

Kaewmati, P., Tan, Q., Higashibayashi, S., Yakiyama, Y. & Sakurai, H., 2017, In : Chemistry Letters. 46, 1, p. 146-148 3 p.

Research output: Contribution to journalArticle

Chirality
X ray crystallography
Single crystals
Derivatives
Crystals
2016
25 Citations (Scopus)

Bowl Inversion and Electronic Switching of Buckybowls on Gold

Fujii, S., Ziatdinov, M., Higashibayashi, S., Sakurai, H. & Kiguchi, M., 2016 Sep 21, In : Journal of the American Chemical Society. 138, 37, p. 12142-12149 8 p.

Research output: Contribution to journalArticle

Scanning Tunnelling Microscopy
Scanning tunneling microscopy
Gold
Molecules
Metals
16 Citations (Scopus)

Redox-Dependent Transformation of a Hydrazinobuckybowl between Curved and Planar Geometries

Higashibayashi, S., Pandit, P., Haruki, R., Adachi, S. I. & Kumai, R., 2016 Aug 26, In : Angewandte Chemie - International Edition. 55, 36, p. 10830-10834 5 p.

Research output: Contribution to journalArticle

hydrazine
Redox reactions
Hydrazine
Chemical shift
Discrete Fourier transforms
9 Citations (Scopus)

Synthesis of Hydroxysumanene and Substituent Effect of Hydroxy Group on Bowl Inversion Dynamics and Electronic Structure

Ngamsomprasert, N., Panda, G., Higashibayashi, S. & Sakurai, H., 2016 Dec 2, In : Journal of Organic Chemistry. 81, 23, p. 11978-11981 4 p.

Research output: Contribution to journalArticle

Electronic structure
Discrete Fourier transforms
Nuclear magnetic resonance
Oxidation
Electrons
12 Citations (Scopus)
hydrazine
Oxidation
Chemical reactivity
Hydrazine
X ray analysis
2 Citations (Scopus)

Thermal stability, solubility, and fluorescence property of poly(arylene vinylene ketone)s bearing 1,1′-binaphthylene units

Tsukamoto, T., Maeyama, K., Higashibayashi, S. & Sakurai, H., 2016 Mar 1, In : Reactive and Functional Polymers. 100, p. 123-129 7 p.

Research output: Contribution to journalArticle

Bearings (structural)
ketone
Ketones
Solubility
divinyl benzene
2015
16 Citations (Scopus)

Acid/base-regulated reversible electron transfer disproportionation of N-N linked bicarbazole and biacridine derivatives

Pandit, P., Yamamoto, K., Nakamura, T., Nishimura, K., Kurashige, Y., Yanai, T., Nakamura, G., Masaoka, S., Furukawa, K., Yakiyama, Y., Kawano, M. & Higashibayashi, S., 2015 Jul 1, In : Chemical Science. 6, 7, p. 4160-4173 14 p.

Research output: Contribution to journalArticle

Derivatives
Acids
Electrons
Metabolism
Cations
5 Citations (Scopus)

Acid-regulated electron-transfer disproportionation of a nonsubstituted tetramethyl-biacridine derivative

Yamamoto, K., Nakamura, T. & Higashibayashi, S., 2015, In : Chemistry Letters. 44, 9, p. 1229-1231 3 p.

Research output: Contribution to journalArticle

X ray analysis
Intermetallics
Cations
Derivatives
Crystals
1 Citation (Scopus)

Chiral Sumanene, Triazasumanene, and Related Buckybowls

Higashibayashi, S. & Sakurai, H., 2015 Jan 1, Chemical Science of Electron Systems. Springer Japan, p. 91-106 16 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Chirality
Electrons
Aromatic compounds
Conformations
Derivatives
4 Citations (Scopus)
1 Citation (Scopus)

Intra- and intermolecular reactivity of triplet sumanenetrione

Kanahara, K., Badal, M. D. M. R., Hatano, S., Abe, M., Higashibayashi, S., Takashina, N. & Sakurai, H., 2015, In : Bulletin of the Chemical Society of Japan. 88, 11, p. 1612-1617 6 p.

Research output: Contribution to journalArticle

Benzene
Ketones
Quenching
Phosphorescence
2-Propanol
4 Citations (Scopus)

Investigation of the dynamic behavior of bisumanenyl

Shrestha, B. B., Karanjit, S., Higashibayashi, S., Amaya, T., Hirao, T. & Sakurai, H., 2015 Jan 1, In : Asian Journal of Organic Chemistry. 4, 1, p. 62-68 7 p.

Research output: Contribution to journalArticle

Energy barriers
Density functional theory
Nuclear magnetic resonance
Thermodynamics
Experiments
4 Citations (Scopus)

Synthesis and acid-responsive electron-Transfer disproportionation of non- and tetramesityl-substituted 1,1',9,9'-bicarbazole

Pandit, P., Nakamura, T. & Higashibayashi, S., 2015, In : Chemistry Letters. 44, 10, p. 1336-1338 3 p.

Research output: Contribution to journalArticle

Dimerization
Cations
Derivatives
Crystals
Acids
3 Citations (Scopus)

Synthesis and characterization of poly(arylene vinylene ketone)s bearing 1,1'-binaphthylene units through MizorokiHeck coupling polymerization

Tsukamoto, T., Maeyama, K., Higashibayashi, S. & Sakurai, H., 2015, In : Chemistry Letters. 44, 12, p. 1780-1782 3 p.

Research output: Contribution to journalArticle

divinyl benzene
Bearings (structural)
Ketones
Organic solvents
Thermodynamic stability
4 Citations (Scopus)

Synthesis of organosoluble and fluorescent aromatic polyketones bearing 1,1′-binaphthyl units through Suzuki–Miyaura coupling polymerization

Maeyama, K., Tsukamoto, T., Kumagai, H., Higashibayashi, S. & Sakurai, H., 2015 Nov 22, In : Polymer Bulletin. 72, 11, p. 2903-2916 14 p.

Research output: Contribution to journalArticle

Bearings (structural)
Palladium
Dimethyl Sulfoxide
Carboxylic acids
Organic solvents
2014
4 Citations (Scopus)

Beam-induced graphitic carbon cage transformation from sumanene aggregates

Fujita, J. I., Tachi, M., Murakami, K., Sakurai, H., Morita, Y., Higashibayashi, S. & Takeguchi, M., 2014 Jan 29, In : Applied Physics Letters. 104, 4, 043107.

Research output: Contribution to journalArticle

carbon
piles
molecules
electron beams
dosage
8 Citations (Scopus)

Columnar/herringbone dual crystal packing of pyrenylsumanene and its photophysical properties

Shrestha, B. B., Higashibayashi, S. & Sakurai, H., 2014 Apr 11, In : Beilstein Journal of Organic Chemistry. 10, p. 841-847 7 p.

Research output: Contribution to journalArticle

Crystals
Quantum yield
Monomers
Single crystals
Crystalline materials
18 Citations (Scopus)

Correlation between bowl-inversion energy and bowl depth in substituted sumanenes

Shrestha, B. B., Karanjit, S., Higashibayashi, S. & Sakurai, H., 2014, In : Pure and Applied Chemistry. 86, 5, p. 747-753 7 p.

Research output: Contribution to journalArticle

Potential energy
Density functional theory
Nuclear magnetic resonance
Spectroscopy
Experiments
8 Citations (Scopus)

DFT studies of mechanism and origin of stereoselectivity of palladium-catalyzed cyclotrimerization reactions affording syn-tris(norborneno) benzenes

Yamanaka, M., Morishima, M., Shibata, Y., Higashibayashi, S. & Sakurai, H., 2014 Jun 23, In : Organometallics. 33, 12, p. 3060-3068 9 p.

Research output: Contribution to journalArticle

Stereoselectivity
Palladium
Alkenes
Benzene
Discrete Fourier transforms
12 Citations (Scopus)

Eclipsed columnar packing in crystal structure of sumanenetrione

Shrestha, B. B., Morita, Y., Kojima, T., Kawano, M., Higashibayashi, S. & Sakurai, H., 2014, In : Chemistry Letters. 43, 8, p. 1294-1296 3 p.

Research output: Contribution to journalArticle

Crystal structure
Single crystals
Derivatives
Molecules
Direction compound
4 Citations (Scopus)
Fullerenes
Benzene Derivatives
Aromatization
Aromatic Hydrocarbons
Carbon Nanotubes
3 Citations (Scopus)

Sumanenetrione anions generated by electrochemical and chemical reduction

Higashibayashi, S., Shrestha, B. B., Morita, Y., Ehara, M., Ohkubo, K., Fukuzumi, S. & Sakurai, H., 2014, In : Chemistry Letters. 43, 8, p. 1297-1299 3 p.

Research output: Contribution to journalArticle

Anions
Ground state
Cyclic voltammetry
Paramagnetic resonance
Absorption spectra
7 Citations (Scopus)
Dimethylformamide
palladium
Palladium
polymerization
Polymerization
2013

Erratum: Enantioselective synthesis of a chiral nitrogen-doped buckybowl (Nature Communications (2012) 3 (891) DOI: 10.1038/ncomms1896)

Tan, Q., Higashibayashi, S., Karanjit, S. & Sakurai, H., 2013, In : Nature Communications. 4, 1314.

Research output: Contribution to journalComment/debate

Nitrogen
communication
nitrogen
synthesis
42 Citations (Scopus)

Fluorinated and trifluoromethylated corannulenes

Schmidt, B. M., Topolinski, B., Yamada, M., Higashibayashi, S., Shionoya, M., Sakurai, H. & Lentz, D., 2013 Oct 4, In : Chemistry - A European Journal. 19, 41, p. 13872-13880 9 p.

Research output: Contribution to journalArticle

Bearings (structural)
Fluorination
Electrons
X ray analysis
Molecular crystals
5 Citations (Scopus)

Jet spectroscopy of buckybowl: Electronic and vibrational structures in the S0 and S1 states of triphenylene and sumanene

Kunishige, S., Kawabata, M., Baba, M., Yamanaka, T., Morita, Y., Higashibayashi, S. & Sakurai, H., 2013 Jul 28, In : Journal of Chemical Physics. 139, 4, 044313.

Research output: Contribution to journalArticle

Fluorescence
Spectroscopy
electronic structure
fluorescence
spectroscopy