γ-Silylboronates in the chiral Brønsted acid-catalysed allylboration of aldehydes

Pablo Barrio, Elsa Rodríguez, Kodai Saito, Santos Fustero, Takahiko Akiyama

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The use of functionalised allylboronic esters in the catalytic enantioselective allylboration of aldehydes is described for the first time. γ-Silylallyl pinacolate derivatives give rise to α-silyl homoallylic alcohols in high yields, with complete diastereoselectivities and high enantioselectivities, in most of the cases. The usefulness of such intermediates is showcased by their transformation into fluorinated allylic alcohols. This journal is

Original languageEnglish
Pages (from-to)5246-5249
Number of pages4
JournalChemical Communications
Volume51
Issue number25
DOIs
Publication statusPublished - 2015 Mar 28
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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