1,4-Asymmetric induction using a cobalt alkyne complex

Yujiro Hayashi, Hirofumi Yamaguchi, Maya Toyoshima, Satoshi Nasu, Koji Ochiai, Mitsuru Shoji

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Remote stereocontrol is a difficult topic in current organic synthesis. We have developed a highly diastereoselective 1,4-asymmetric induction using a cobalt alkyne complex. This is the first example of using a cobalt alkyne complex for a stereoselective reaction via 1,4-chelation. Both anti and syn isomers were stereoselectively synthesized using two different methods.

Original languageEnglish
Pages (from-to)163-165
Number of pages3
JournalOrganometallics
Volume27
Issue number2
DOIs
Publication statusPublished - 2008 Jan 28

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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  • Cite this

    Hayashi, Y., Yamaguchi, H., Toyoshima, M., Nasu, S., Ochiai, K., & Shoji, M. (2008). 1,4-Asymmetric induction using a cobalt alkyne complex. Organometallics, 27(2), 163-165. https://doi.org/10.1021/om700961e