1,4-Asymmetric induction using a cobalt alkyne complex

Yujiro Hayashi, Hirofumi Yamaguchi, Maya Toyoshima, Satoshi Nasu, Koji Ochiai, Mitsuru Shoji

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Remote stereocontrol is a difficult topic in current organic synthesis. We have developed a highly diastereoselective 1,4-asymmetric induction using a cobalt alkyne complex. This is the first example of using a cobalt alkyne complex for a stereoselective reaction via 1,4-chelation. Both anti and syn isomers were stereoselectively synthesized using two different methods.

Original languageEnglish
Pages (from-to)163-165
Number of pages3
JournalOrganometallics
Volume27
Issue number2
DOIs
Publication statusPublished - 2008 Jan 28
Externally publishedYes

Fingerprint

Alkynes
alkynes
Cobalt
induction
cobalt
chelation
Chelation
Isomers
isomers
synthesis

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Hayashi, Y., Yamaguchi, H., Toyoshima, M., Nasu, S., Ochiai, K., & Shoji, M. (2008). 1,4-Asymmetric induction using a cobalt alkyne complex. Organometallics, 27(2), 163-165. https://doi.org/10.1021/om700961e

1,4-Asymmetric induction using a cobalt alkyne complex. / Hayashi, Yujiro; Yamaguchi, Hirofumi; Toyoshima, Maya; Nasu, Satoshi; Ochiai, Koji; Shoji, Mitsuru.

In: Organometallics, Vol. 27, No. 2, 28.01.2008, p. 163-165.

Research output: Contribution to journalArticle

Hayashi, Y, Yamaguchi, H, Toyoshima, M, Nasu, S, Ochiai, K & Shoji, M 2008, '1,4-Asymmetric induction using a cobalt alkyne complex', Organometallics, vol. 27, no. 2, pp. 163-165. https://doi.org/10.1021/om700961e
Hayashi Y, Yamaguchi H, Toyoshima M, Nasu S, Ochiai K, Shoji M. 1,4-Asymmetric induction using a cobalt alkyne complex. Organometallics. 2008 Jan 28;27(2):163-165. https://doi.org/10.1021/om700961e
Hayashi, Yujiro ; Yamaguchi, Hirofumi ; Toyoshima, Maya ; Nasu, Satoshi ; Ochiai, Koji ; Shoji, Mitsuru. / 1,4-Asymmetric induction using a cobalt alkyne complex. In: Organometallics. 2008 ; Vol. 27, No. 2. pp. 163-165.
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