(+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol

Hiroyuki Hosomi; Shigeru Ohba; Ken Ohmori; Tetsuo Obitsu; Yasuyuki Ogawa; Yuichi Ishikawa; Shosuke Yamamura; Shigeru Nishiyama

doi:10.1107/S0108270100003371

(+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol

Hiroyuki Hosomi, Shigeru Ohba, Ken Ohmori, Tetsuo Obitsu, Yasuyuki Ogawa, Yuichi Ishikawa, Shosuke Yamamura, Shigeru Nishiyama

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The absolute configuration was determined for the title compound. It was prepared in a synthetic study on the natural products, bryostatins. There were 163 Friedel pairs, which were not averaged. The completeness of symmetry unique reactions was 93.3%, which was due to the blind region of the low temperature apparatus. The hydroxyl H atom was located from a difference synthesis. The absolute structure was determined based on a Flack parameter value of 0.03 (3).

Original language	English
Pages (from-to)	e142-e143
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	56
Issue number	4
DOIs	https://doi.org/10.1107/S0108270100003371
Publication status	Published - 2000 Jan 1

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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(+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol. / Hosomi, Hiroyuki; Ohba, Shigeru; Ohmori, Ken; Obitsu, Tetsuo; Ogawa, Yasuyuki; Ishikawa, Yuichi; Yamamura, Shosuke; Nishiyama, Shigeru.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 4, 01.01.2000, p. e142-e143.

Research output: Contribution to journal › Article › peer-review

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abstract = "The absolute configuration was determined for the title compound. It was prepared in a synthetic study on the natural products, bryostatins. There were 163 Friedel pairs, which were not averaged. The completeness of symmetry unique reactions was 93.3%, which was due to the blind region of the low temperature apparatus. The hydroxyl H atom was located from a difference synthesis. The absolute structure was determined based on a Flack parameter value of 0.03 (3).",

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T1 - (+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol

AU - Hosomi, Hiroyuki

AU - Ohba, Shigeru

AU - Ohmori, Ken

AU - Obitsu, Tetsuo

AU - Ogawa, Yasuyuki

AU - Ishikawa, Yuichi

AU - Yamamura, Shosuke

AU - Nishiyama, Shigeru

PY - 2000/1/1

Y1 - 2000/1/1

N2 - The absolute configuration was determined for the title compound. It was prepared in a synthetic study on the natural products, bryostatins. There were 163 Friedel pairs, which were not averaged. The completeness of symmetry unique reactions was 93.3%, which was due to the blind region of the low temperature apparatus. The hydroxyl H atom was located from a difference synthesis. The absolute structure was determined based on a Flack parameter value of 0.03 (3).

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