(+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol

Hiroyuki Hosomi, Shigeru Ohba, Ken Ohmori, Tetsuo Obitsu, Yasuyuki Ogawa, Yuichi Ishikawa, Shosuke Yamamura, Shigeru Nishiyama

Research output: Contribution to journalArticle

Abstract

The absolute configuration was determined for the title compound. It was prepared in a synthetic study on the natural products, bryostatins. There were 163 Friedel pairs, which were not averaged. The completeness of symmetry unique reactions was 93.3%, which was due to the blind region of the low temperature apparatus. The hydroxyl H atom was located from a difference synthesis. The absolute structure was determined based on a Flack parameter value of 0.03 (3).

Original languageEnglish
Pages (from-to)e142-e143
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number4
Publication statusPublished - 2000

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Bryostatins
Biological Products
Hydroxyl Radical
Atoms
Temperature

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

Hosomi, H., Ohba, S., Ohmori, K., Obitsu, T., Ogawa, Y., Ishikawa, Y., ... Nishiyama, S. (2000). (+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol. Acta Crystallographica Section C: Crystal Structure Communications, 56(4), e142-e143.

(+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol. / Hosomi, Hiroyuki; Ohba, Shigeru; Ohmori, Ken; Obitsu, Tetsuo; Ogawa, Yasuyuki; Ishikawa, Yuichi; Yamamura, Shosuke; Nishiyama, Shigeru.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 4, 2000, p. e142-e143.

Research output: Contribution to journalArticle

Hosomi, H, Ohba, S, Ohmori, K, Obitsu, T, Ogawa, Y, Ishikawa, Y, Yamamura, S & Nishiyama, S 2000, '(+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol', Acta Crystallographica Section C: Crystal Structure Communications, vol. 56, no. 4, pp. e142-e143.
Hosomi, Hiroyuki ; Ohba, Shigeru ; Ohmori, Ken ; Obitsu, Tetsuo ; Ogawa, Yasuyuki ; Ishikawa, Yuichi ; Yamamura, Shosuke ; Nishiyama, Shigeru. / (+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol. In: Acta Crystallographica Section C: Crystal Structure Communications. 2000 ; Vol. 56, No. 4. pp. e142-e143.
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AU - Hosomi, Hiroyuki

AU - Ohba, Shigeru

AU - Ohmori, Ken

AU - Obitsu, Tetsuo

AU - Ogawa, Yasuyuki

AU - Ishikawa, Yuichi

AU - Yamamura, Shosuke

AU - Nishiyama, Shigeru

PY - 2000

Y1 - 2000

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