(+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol

Hiroyuki Hosomi, Shigeru Ohba, Ken Ohmori, Tetsuo Obitsu, Yasuyuki Ogawa, Yuichi Ishikawa, Shosuke Yamamura, Shigeru Nishiyama

Research output: Contribution to journalArticle

Abstract

The absolute configuration was determined for the title compound. It was prepared in a synthetic study on the natural products, bryostatins. There were 163 Friedel pairs, which were not averaged. The completeness of symmetry unique reactions was 93.3%, which was due to the blind region of the low temperature apparatus. The hydroxyl H atom was located from a difference synthesis. The absolute structure was determined based on a Flack parameter value of 0.03 (3).

Original languageEnglish
Pages (from-to)e142-e143
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number4
DOIs
Publication statusPublished - 2000 Jan 1

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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