A biphasic sol–gel route to synthesize anatase TiO 2 particles under controlled conditions and their DSSC application

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8 Citations (Scopus)

Abstract

A biphasic sol–gel method was introduced to reduce a high hydrolysis rate of metal alkoxides and control a morphological evolution of metal oxides. Titanium tetraisopropoxide (TTIP) was dissolved in an organic solvent which was immiscible with water. The TTIP solution was then contacted with water or pH-controlled aqueous solutions to promote the hydrolysis and the polycondensation reaction through the mass transfer across the organic/aqueous interface. Anatase TiO 2 was formed in any conditions employed in the present work at reaction temperatures of 80 °C or below. The morphology of TiO 2 particles obtained was largely dependent on the kind of organic solvents. It was basically the aggregation of nanoparticles to give submicrometer-sized secondary particles with or without a regular shape. Heptane was found to be suitable to obtain spherical TiO 2 large particles, which were evaluated as a photoanode material in dye-sensitized solar cells. Actually the large TiO 2 particles worked well as the light scattering layer when applying them to a double-layered phtoanode, which showed an energy conversion efficiency of 5.67% with a high short-circuit photocurrent density of 14.1 mA cm −2 .

Original languageEnglish
Pages (from-to)427-435
Number of pages9
JournalJournal of Asian Ceramic Societies
Volume5
Issue number4
DOIs
Publication statusPublished - 2017 Dec

Keywords

  • Dye-sensitized solar cells
  • Sol–gel method
  • Titanium dioxide
  • Titanium tetraisopropoxide

ASJC Scopus subject areas

  • Ceramics and Composites

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