A chiral photochromic Schiff base: (R)-4-bromo-2-[(1-phenylethyl) iminomethyl]phenol

Takashiro Akitsu, Yasuaki Einaga

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

The title chiral photochromic Schiff base compound, C15H 14BrNO, was synthesized from (R)-1-phenylethylamine and 5-bromosalicylaldehyde. The molecule is the phenolimine tautomer, the C=N and N-C bond distances being 1.261(7) and 1.482 (7) Å, respectively. There is an intramolecular O-H⋯N hydrogen bond with an O⋯N distance of 2.593 (7) Å.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number10
DOIs
Publication statusPublished - 2006 Oct

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Phenethylamines
Schiff Bases
Phenol
phenols
imines
Phenols
Hydrogen
Hydrogen bonds
Molecules
tautomers
hydrogen bonds
molecules
5-bromosalicylaldehyde

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

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abstract = "The title chiral photochromic Schiff base compound, C15H 14BrNO, was synthesized from (R)-1-phenylethylamine and 5-bromosalicylaldehyde. The molecule is the phenolimine tautomer, the C=N and N-C bond distances being 1.261(7) and 1.482 (7) {\AA}, respectively. There is an intramolecular O-H⋯N hydrogen bond with an O⋯N distance of 2.593 (7) {\AA}.",
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N2 - The title chiral photochromic Schiff base compound, C15H 14BrNO, was synthesized from (R)-1-phenylethylamine and 5-bromosalicylaldehyde. The molecule is the phenolimine tautomer, the C=N and N-C bond distances being 1.261(7) and 1.482 (7) Å, respectively. There is an intramolecular O-H⋯N hydrogen bond with an O⋯N distance of 2.593 (7) Å.

AB - The title chiral photochromic Schiff base compound, C15H 14BrNO, was synthesized from (R)-1-phenylethylamine and 5-bromosalicylaldehyde. The molecule is the phenolimine tautomer, the C=N and N-C bond distances being 1.261(7) and 1.482 (7) Å, respectively. There is an intramolecular O-H⋯N hydrogen bond with an O⋯N distance of 2.593 (7) Å.

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