Abstract
In the crystal structure of tetrakis(μ-4-chlorophenoxyisobutyrato-O, O′)di(methanol-O)dicopper(II) dimethanol solvate, [Cu(pciba)2(CH3OH)]2.2CH3OH (pcibaH is 4-chlorophenoxyisobutyric acid, C10H11ClO3), there is a dinuclear CuII complex which has a typical cage structure with a Cu⋯Cu distance of 2.6437 (4) Å. The magnetic -2J value is 360cm-1 (H = -2JS1.S2). In the crystal structure of trans-bis(4-chlorophenoxyisobutyrato-O,O′) dipyridinecopper(II), [Cu(pciba)2-(C5H5N)2], the monomeric CuII complex has a distorted octahedral coordination.
| Original language | English |
|---|---|
| Pages (from-to) | 193-195 |
| Number of pages | 3 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 54 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 1998 Feb 15 |
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
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Kani, Y., Ohba, S., Matsushima, H., & Tokii, T. (1998). A dimeric copper(II) 4-chlorophenoxyisobutyrate adduct with methanol and a monomeric copper(II) 4-chlorophenoxyisobutyrate adduct with pyridine. Acta Crystallographica Section C: Crystal Structure Communications, 54(2), 193-195. https://doi.org/10.1107/S0108270197012973