Abstract
In the crystal structure of tetrakis(μ-4-chlorophenoxyisobutyrato-O, O′)di(methanol-O)dicopper(II) dimethanol solvate, [Cu(pciba)2(CH3OH)]2.2CH3OH (pcibaH is 4-chlorophenoxyisobutyric acid, C10H11ClO3), there is a dinuclear CuII complex which has a typical cage structure with a Cu⋯Cu distance of 2.6437 (4) Å. The magnetic -2J value is 360cm-1 (H = -2JS1.S2). In the crystal structure of trans-bis(4-chlorophenoxyisobutyrato-O,O′) dipyridinecopper(II), [Cu(pciba)2-(C5H5N)2], the monomeric CuII complex has a distorted octahedral coordination.
| Original language | English |
|---|---|
| Pages (from-to) | 193-195 |
| Number of pages | 3 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 54 |
| Issue number | 2 |
| Publication status | Published - 1998 Feb 15 |
Fingerprint
ASJC Scopus subject areas
- Condensed Matter Physics
- Structural Biology
Cite this
A dimeric copper(II) 4-chlorophenoxyisobutyrate adduct with methanol and a monomeric copper(II) 4-chlorophenoxyisobutyrate adduct with pyridine. / Kani, Yoshiyuki; Ohba, Shigeru; Matsushima, Hideaki; Tokii, Tadashi.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 54, No. 2, 15.02.1998, p. 193-195.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - A dimeric copper(II) 4-chlorophenoxyisobutyrate adduct with methanol and a monomeric copper(II) 4-chlorophenoxyisobutyrate adduct with pyridine
AU - Kani, Yoshiyuki
AU - Ohba, Shigeru
AU - Matsushima, Hideaki
AU - Tokii, Tadashi
PY - 1998/2/15
Y1 - 1998/2/15
N2 - In the crystal structure of tetrakis(μ-4-chlorophenoxyisobutyrato-O, O′)di(methanol-O)dicopper(II) dimethanol solvate, [Cu(pciba)2(CH3OH)]2.2CH3OH (pcibaH is 4-chlorophenoxyisobutyric acid, C10H11ClO3), there is a dinuclear CuII complex which has a typical cage structure with a Cu⋯Cu distance of 2.6437 (4) Å. The magnetic -2J value is 360cm-1 (H = -2JS1.S2). In the crystal structure of trans-bis(4-chlorophenoxyisobutyrato-O,O′) dipyridinecopper(II), [Cu(pciba)2-(C5H5N)2], the monomeric CuII complex has a distorted octahedral coordination.
AB - In the crystal structure of tetrakis(μ-4-chlorophenoxyisobutyrato-O, O′)di(methanol-O)dicopper(II) dimethanol solvate, [Cu(pciba)2(CH3OH)]2.2CH3OH (pcibaH is 4-chlorophenoxyisobutyric acid, C10H11ClO3), there is a dinuclear CuII complex which has a typical cage structure with a Cu⋯Cu distance of 2.6437 (4) Å. The magnetic -2J value is 360cm-1 (H = -2JS1.S2). In the crystal structure of trans-bis(4-chlorophenoxyisobutyrato-O,O′) dipyridinecopper(II), [Cu(pciba)2-(C5H5N)2], the monomeric CuII complex has a distorted octahedral coordination.
UR - http://www.scopus.com/inward/record.url?scp=0032003615&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0032003615&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0032003615
VL - 54
SP - 193
EP - 195
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 2
ER -