A dimeric copper(II) 4-chlorophenoxyisobutyrate adduct with methanol and a monomeric copper(II) 4-chlorophenoxyisobutyrate adduct with pyridine

Yoshiyuki Kani; Shigeru Ohba; Hideaki Matsushima; Tadashi Tokii

doi:10.1107/S0108270197012973

A dimeric copper(II) 4-chlorophenoxyisobutyrate adduct with methanol and a monomeric copper(II) 4-chlorophenoxyisobutyrate adduct with pyridine

Yoshiyuki Kani, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

In the crystal structure of tetrakis(μ-4-chlorophenoxyisobutyrato-O, O′)di(methanol-O)dicopper(II) dimethanol solvate, [Cu(pciba)₂(CH₃OH)]₂.2CH₃OH (pcibaH is 4-chlorophenoxyisobutyric acid, C₁₀H₁₁ClO₃), there is a dinuclear Cu^II complex which has a typical cage structure with a Cu⋯Cu distance of 2.6437 (4) Å. The magnetic -2J value is 360cm^-1 (H = -2JS₁.S₂). In the crystal structure of trans-bis(4-chlorophenoxyisobutyrato-O,O′) dipyridinecopper(II), [Cu(pciba)₂-(C₅H₅N)₂], the monomeric Cu^II complex has a distorted octahedral coordination.

Original language	English
Pages (from-to)	193-195
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	2
DOIs	https://doi.org/10.1107/S0108270197012973
Publication status	Published - 1998 Feb 15

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ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

Cite this

Kani, Y., Ohba, S., Matsushima, H., & Tokii, T. (1998). A dimeric copper(II) 4-chlorophenoxyisobutyrate adduct with methanol and a monomeric copper(II) 4-chlorophenoxyisobutyrate adduct with pyridine. Acta Crystallographica Section C: Crystal Structure Communications, 54(2), 193-195. https://doi.org/10.1107/S0108270197012973

A dimeric copper(II) 4-chlorophenoxyisobutyrate adduct with methanol and a monomeric copper(II) 4-chlorophenoxyisobutyrate adduct with pyridine. / Kani, Yoshiyuki; Ohba, Shigeru; Matsushima, Hideaki; Tokii, Tadashi.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 54, No. 2, 15.02.1998, p. 193-195.

Research output: Contribution to journal › Article

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abstract = "In the crystal structure of tetrakis(μ-4-chlorophenoxyisobutyrato-O, O′)di(methanol-O)dicopper(II) dimethanol solvate, [Cu(pciba)2(CH3OH)]2.2CH3OH (pcibaH is 4-chlorophenoxyisobutyric acid, C10H11ClO3), there is a dinuclear CuII complex which has a typical cage structure with a Cu⋯Cu distance of 2.6437 (4) {\AA}. The magnetic -2J value is 360cm-1 (H = -2JS1.S2). In the crystal structure of trans-bis(4-chlorophenoxyisobutyrato-O,O′) dipyridinecopper(II), [Cu(pciba)2-(C5H5N)2], the monomeric CuII complex has a distorted octahedral coordination.",

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N2 - In the crystal structure of tetrakis(μ-4-chlorophenoxyisobutyrato-O, O′)di(methanol-O)dicopper(II) dimethanol solvate, [Cu(pciba)2(CH3OH)]2.2CH3OH (pcibaH is 4-chlorophenoxyisobutyric acid, C10H11ClO3), there is a dinuclear CuII complex which has a typical cage structure with a Cu⋯Cu distance of 2.6437 (4) Å. The magnetic -2J value is 360cm-1 (H = -2JS1.S2). In the crystal structure of trans-bis(4-chlorophenoxyisobutyrato-O,O′) dipyridinecopper(II), [Cu(pciba)2-(C5H5N)2], the monomeric CuII complex has a distorted octahedral coordination.

AB - In the crystal structure of tetrakis(μ-4-chlorophenoxyisobutyrato-O, O′)di(methanol-O)dicopper(II) dimethanol solvate, [Cu(pciba)2(CH3OH)]2.2CH3OH (pcibaH is 4-chlorophenoxyisobutyric acid, C10H11ClO3), there is a dinuclear CuII complex which has a typical cage structure with a Cu⋯Cu distance of 2.6437 (4) Å. The magnetic -2J value is 360cm-1 (H = -2JS1.S2). In the crystal structure of trans-bis(4-chlorophenoxyisobutyrato-O,O′) dipyridinecopper(II), [Cu(pciba)2-(C5H5N)2], the monomeric CuII complex has a distorted octahedral coordination.

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10.1107/S0108270197012973