A dimeric copper(II) bis(4-chlorophenoxy)-acetate adduct with dimethylformamide

Yoshiyuki Kani; Masanobu Tsuchimoto; Shigeru Ohba; Hideaki Matsushima; Masakazu Noguchi; Tadashi Tokii

doi:10.1107/S0108270198014899

A dimeric copper(II) bis(4-chlorophenoxy)-acetate adduct with dimethylformamide

Yoshiyuki Kani, Masanobu Tsuchimoto, Shigeru Ohba, Hideaki Matsushima, Masakazu Noguchi, Tadashi Tokii

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The crystal structure of tetrakis[μ-bis(4-chlorophenoxy)-acetato-O:O′]bis[(dimethylformamide-O) copper(II)], [Cu(bpca)₂(dmf)]₂ [bpca is bis(4-chlorophenoxy)acetate, C₁₄H₉Cl₂O₄; dmf is dimethylformamide, C₃H₇NO], consists of a dinuclear Cu¹¹ complex which has a typical cage structure, with a Cu. . .Cu distance of 2.685 (1) Å. The magnetic -2J value is 361 cm^-1 (H = -2JS₁S₂).

Original language	English
Pages (from-to)	316-318
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	55
Issue number	3
DOIs	https://doi.org/10.1107/S0108270198014899
Publication status	Published - 1999 Mar 15

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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title = "A dimeric copper(II) bis(4-chlorophenoxy)-acetate adduct with dimethylformamide",

abstract = "The crystal structure of tetrakis[μ-bis(4-chlorophenoxy)-acetato-O:O′]bis[(dimethylformamide-O) copper(II)], [Cu(bpca)2(dmf)]2 [bpca is bis(4-chlorophenoxy)acetate, C14H9Cl2O4; dmf is dimethylformamide, C3H7NO], consists of a dinuclear Cu11 complex which has a typical cage structure, with a Cu. . .Cu distance of 2.685 (1) {\AA}. The magnetic -2J value is 361 cm-1 (H = -2JS1S2).",

author = "Yoshiyuki Kani and Masanobu Tsuchimoto and Shigeru Ohba and Hideaki Matsushima and Masakazu Noguchi and Tadashi Tokii",

year = "1999",

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language = "English",

volume = "55",

pages = "316--318",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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T1 - A dimeric copper(II) bis(4-chlorophenoxy)-acetate adduct with dimethylformamide

AU - Kani, Yoshiyuki

AU - Tsuchimoto, Masanobu

AU - Ohba, Shigeru

AU - Matsushima, Hideaki

AU - Noguchi, Masakazu

AU - Tokii, Tadashi

PY - 1999/3/15

Y1 - 1999/3/15

N2 - The crystal structure of tetrakis[μ-bis(4-chlorophenoxy)-acetato-O:O′]bis[(dimethylformamide-O) copper(II)], [Cu(bpca)2(dmf)]2 [bpca is bis(4-chlorophenoxy)acetate, C14H9Cl2O4; dmf is dimethylformamide, C3H7NO], consists of a dinuclear Cu11 complex which has a typical cage structure, with a Cu. . .Cu distance of 2.685 (1) Å. The magnetic -2J value is 361 cm-1 (H = -2JS1S2).

AB - The crystal structure of tetrakis[μ-bis(4-chlorophenoxy)-acetato-O:O′]bis[(dimethylformamide-O) copper(II)], [Cu(bpca)2(dmf)]2 [bpca is bis(4-chlorophenoxy)acetate, C14H9Cl2O4; dmf is dimethylformamide, C3H7NO], consists of a dinuclear Cu11 complex which has a typical cage structure, with a Cu. . .Cu distance of 2.685 (1) Å. The magnetic -2J value is 361 cm-1 (H = -2JS1S2).

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A dimeric copper(II) bis(4-chlorophenoxy)-acetate adduct with dimethylformamide

Abstract

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