A facile method of synthesizing size-controlled hollow cyanoacrylate nanoparticles for transparent superhydrophobic/oleophobic surfaces

Takeshi Matsubayashi, Mizuki Tenjimbayashi, Kengo Manabe, Kyu Hong Kyung, Bin Ding, Seimei Shiratori

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Hollow nanoparticles have broad technological implications in a wide range of applications. Particularly, they have attracted great attention as functional coatings in applications such as optical devices, which have an optical transparency derived from a low refractive index. However, creating a facile and versatile method that can accurately control the hollow nanoparticle size has proven extremely challenging. Herein, we report a simple, instantly complete, one-pot method, designated the supersaturated gas-cored instant polymerization (SGCIP) method, to synthesize size-controlled hollow cyanoacrylate nanoparticles (HCNPs). The SGCIP method uses supersaturated gas created by mixing two solvents (water and acetone) and the instant polymerization of cyanoacrylate, whereby it demonstrates facile control of the particle diameters ranging from 13 to 1830 nm reproducibly by simply changing the solvent ratio. Moreover, a unique phase transition (from network to particle formation) is observed during the adjustment of the solvent ratio. As a one-concept application, transparent superhydrophobic/oleophobic coatings are achieved by self-assembly of the HCNPs and silanization. The successful synthesis of such fascinating materials may also provide new insights into the design and development of functional hollow nanoparticles for various applications.

Original languageEnglish
Pages (from-to)15877-15883
Number of pages7
JournalRSC Advances
Volume6
Issue number19
DOIs
Publication statusPublished - 2016

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Cyanoacrylates
Nanoparticles
Gases
Polymerization
Coatings
Optical devices
Acetone
Transparency
Self assembly
Refractive index
Phase transitions
Water

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Matsubayashi, T., Tenjimbayashi, M., Manabe, K., Kyung, K. H., Ding, B., & Shiratori, S. (2016). A facile method of synthesizing size-controlled hollow cyanoacrylate nanoparticles for transparent superhydrophobic/oleophobic surfaces. RSC Advances, 6(19), 15877-15883. https://doi.org/10.1039/c6ra00493h

A facile method of synthesizing size-controlled hollow cyanoacrylate nanoparticles for transparent superhydrophobic/oleophobic surfaces. / Matsubayashi, Takeshi; Tenjimbayashi, Mizuki; Manabe, Kengo; Kyung, Kyu Hong; Ding, Bin; Shiratori, Seimei.

In: RSC Advances, Vol. 6, No. 19, 2016, p. 15877-15883.

Research output: Contribution to journalArticle

Matsubayashi, T, Tenjimbayashi, M, Manabe, K, Kyung, KH, Ding, B & Shiratori, S 2016, 'A facile method of synthesizing size-controlled hollow cyanoacrylate nanoparticles for transparent superhydrophobic/oleophobic surfaces', RSC Advances, vol. 6, no. 19, pp. 15877-15883. https://doi.org/10.1039/c6ra00493h
Matsubayashi, Takeshi ; Tenjimbayashi, Mizuki ; Manabe, Kengo ; Kyung, Kyu Hong ; Ding, Bin ; Shiratori, Seimei. / A facile method of synthesizing size-controlled hollow cyanoacrylate nanoparticles for transparent superhydrophobic/oleophobic surfaces. In: RSC Advances. 2016 ; Vol. 6, No. 19. pp. 15877-15883.
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