Abstract
N-pentafluorophenyl maleimide (PFPMI) was synthesized. The homo and copolymers of PFPMI with methyl methacrylate (MMA) were prepared. The refractive indexes of poly(PFPMI) and PMMA are almost the same, 1.4989 and 1.4953 at 532 nm respectively. Therefore, the copolymers of PFPMI and MMA exhibited no light scattering and the film was very transparent. The glass transition temperatures of the PFPMI-co-MMA were in the range of 140°-180°and the refractive indexes were 1.4965-1.4970 with the PFPMI content from 18.8-65 mol%. In addition, the copolymers obtained have high thermal stability (~370°) and low water absorption property.
| Original language | English |
|---|---|
| Title of host publication | POF 2011: 20th International Conference on Plastic Optical Fibers - Conference Proceeding |
| Pages | 139-142 |
| Number of pages | 4 |
| Publication status | Published - 2011 |
| Event | 20th International Conference on Plastic Optical Fibers, POF 2011 - Bilbao, Spain Duration: 2011 Sep 14 → 2011 Sep 16 |
Other
| Other | 20th International Conference on Plastic Optical Fibers, POF 2011 |
|---|---|
| Country | Spain |
| City | Bilbao |
| Period | 11/9/14 → 11/9/16 |
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Keywords
- Methyl methacrylate
- N-pentafluorophenyl maleimide
- POF
- Refractive indexes
- Thermal properties
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Materials Chemistry
- Polymers and Plastics
Cite this
A high glass transition temperature, thermally stable and transparent polymer for plastic optical fiber; a novel copolymer of methyl methacrylate with npentafluorophenyl maleimide. / Okamoto, Yoshiyuki; Lou, Liping; Koike, Kotaro; Koike, Yasuhiro.
POF 2011: 20th International Conference on Plastic Optical Fibers - Conference Proceeding. 2011. p. 139-142.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - A high glass transition temperature, thermally stable and transparent polymer for plastic optical fiber; a novel copolymer of methyl methacrylate with npentafluorophenyl maleimide
AU - Okamoto, Yoshiyuki
AU - Lou, Liping
AU - Koike, Kotaro
AU - Koike, Yasuhiro
PY - 2011
Y1 - 2011
N2 - N-pentafluorophenyl maleimide (PFPMI) was synthesized. The homo and copolymers of PFPMI with methyl methacrylate (MMA) were prepared. The refractive indexes of poly(PFPMI) and PMMA are almost the same, 1.4989 and 1.4953 at 532 nm respectively. Therefore, the copolymers of PFPMI and MMA exhibited no light scattering and the film was very transparent. The glass transition temperatures of the PFPMI-co-MMA were in the range of 140°-180°and the refractive indexes were 1.4965-1.4970 with the PFPMI content from 18.8-65 mol%. In addition, the copolymers obtained have high thermal stability (~370°) and low water absorption property.
AB - N-pentafluorophenyl maleimide (PFPMI) was synthesized. The homo and copolymers of PFPMI with methyl methacrylate (MMA) were prepared. The refractive indexes of poly(PFPMI) and PMMA are almost the same, 1.4989 and 1.4953 at 532 nm respectively. Therefore, the copolymers of PFPMI and MMA exhibited no light scattering and the film was very transparent. The glass transition temperatures of the PFPMI-co-MMA were in the range of 140°-180°and the refractive indexes were 1.4965-1.4970 with the PFPMI content from 18.8-65 mol%. In addition, the copolymers obtained have high thermal stability (~370°) and low water absorption property.
KW - Methyl methacrylate
KW - N-pentafluorophenyl maleimide
KW - POF
KW - Refractive indexes
KW - Thermal properties
UR - http://www.scopus.com/inward/record.url?scp=84879351678&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84879351678&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:84879351678
SP - 139
EP - 142
BT - POF 2011: 20th International Conference on Plastic Optical Fibers - Conference Proceeding
ER -