A monomeric and a dimeric copper(II) trigonelline adduct with chloride, and a dimeric copper(II) 1-methyl-2-pyrrolecarboxylate adduct with 3-methylpyridine

Hiroo Nakagawa; Yoshiyuki Kani; Masanobu Tsuchimoto; Shigeru Ohba; Matsushima Hideaki; Tadashi Tokii

doi:10.1107/S0108270199001985

A monomeric and a dimeric copper(II) trigonelline adduct with chloride, and a dimeric copper(II) 1-methyl-2-pyrrolecarboxylate adduct with 3-methylpyridine

Hiroo Nakagawa, Yoshiyuki Kani, Masanobu Tsuchimoto, Shigeru Ohba, Matsushima Hideaki, Tadashi Tokii

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

In the crystal structure of trans-dichlorobis(trigonelline-O,O′)copper(II) (trigonelline is N-methylpyridinium-3-carboxylate), [CuCl₂(C₇H₇NO₂)₂], (I), the monomeric Cu^II complex has a distorted octahedral coordination. In the crystal structure of tetrakis(μ-trigonelline-O:O′)-bis[chlorocopper(II)] dichloride octahydrate, [Cu₂Cl₂-(C₇H₇NO₂) ₄]Cl₂·8H₂O, (II), the dinuclear Cu^II complex has a slightly elongated cage structure, with a Cu⋯Cu distance of 2.770 (1) Å. In the crystal structure of tetrakis[μ-(1-methylpyrrole-2-carboxylato)-O:O′]-bis[(3-methylpyridine- N)copper(II)], [Cu₂(C₆H₆NO₂)₄-(C ₆H₇N)₂], (III), the dinuclear Cu^II complex has a cage structure, with a Cu⋯Cu distance of 2.671 (1) Å. The magnetic -2J value for (III) is 343 cm^-1 (H = -2JS₁.S₂).

Original language	English
Pages (from-to)	882-886
Number of pages	5
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	55
Issue number	6
DOIs	https://doi.org/10.1107/S0108270199001985
Publication status	Published - 1999 Jun 15
Externally published	Yes

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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10.1107/S0108270199001985

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A monomeric and a dimeric copper(II) trigonelline adduct with chloride, and a dimeric copper(II) 1-methyl-2-pyrrolecarboxylate adduct with 3-methylpyridine. / Nakagawa, Hiroo; Kani, Yoshiyuki; Tsuchimoto, Masanobu et al.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 55, No. 6, 15.06.1999, p. 882-886.

Research output: Contribution to journal › Article › peer-review

Nakagawa, H, Kani, Y, Tsuchimoto, M, Ohba, S, Hideaki, M & Tokii, T 1999, 'A monomeric and a dimeric copper(II) trigonelline adduct with chloride, and a dimeric copper(II) 1-methyl-2-pyrrolecarboxylate adduct with 3-methylpyridine', Acta Crystallographica Section C: Crystal Structure Communications, vol. 55, no. 6, pp. 882-886. https://doi.org/10.1107/S0108270199001985

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title = "A monomeric and a dimeric copper(II) trigonelline adduct with chloride, and a dimeric copper(II) 1-methyl-2-pyrrolecarboxylate adduct with 3-methylpyridine",

abstract = "In the crystal structure of trans-dichlorobis(trigonelline-O,O′)copper(II) (trigonelline is N-methylpyridinium-3-carboxylate), [CuCl2(C7H7NO2)2], (I), the monomeric CuII complex has a distorted octahedral coordination. In the crystal structure of tetrakis(μ-trigonelline-O:O′)-bis[chlorocopper(II)] dichloride octahydrate, [Cu2Cl2-(C7H7NO2) 4]Cl2·8H2O, (II), the dinuclear CuII complex has a slightly elongated cage structure, with a Cu⋯Cu distance of 2.770 (1) {\AA}. In the crystal structure of tetrakis[μ-(1-methylpyrrole-2-carboxylato)-O:O′]-bis[(3-methylpyridine- N)copper(II)], [Cu2(C6H6NO2)4-(C 6H7N)2], (III), the dinuclear CuII complex has a cage structure, with a Cu⋯Cu distance of 2.671 (1) {\AA}. The magnetic -2J value for (III) is 343 cm-1 (H = -2JS1.S2).",

author = "Hiroo Nakagawa and Yoshiyuki Kani and Masanobu Tsuchimoto and Shigeru Ohba and Matsushima Hideaki and Tadashi Tokii",

year = "1999",

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doi = "10.1107/S0108270199001985",

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T1 - A monomeric and a dimeric copper(II) trigonelline adduct with chloride, and a dimeric copper(II) 1-methyl-2-pyrrolecarboxylate adduct with 3-methylpyridine

AU - Nakagawa, Hiroo

AU - Kani, Yoshiyuki

AU - Tsuchimoto, Masanobu

AU - Ohba, Shigeru

AU - Hideaki, Matsushima

AU - Tokii, Tadashi

PY - 1999/6/15

Y1 - 1999/6/15

N2 - In the crystal structure of trans-dichlorobis(trigonelline-O,O′)copper(II) (trigonelline is N-methylpyridinium-3-carboxylate), [CuCl2(C7H7NO2)2], (I), the monomeric CuII complex has a distorted octahedral coordination. In the crystal structure of tetrakis(μ-trigonelline-O:O′)-bis[chlorocopper(II)] dichloride octahydrate, [Cu2Cl2-(C7H7NO2) 4]Cl2·8H2O, (II), the dinuclear CuII complex has a slightly elongated cage structure, with a Cu⋯Cu distance of 2.770 (1) Å. In the crystal structure of tetrakis[μ-(1-methylpyrrole-2-carboxylato)-O:O′]-bis[(3-methylpyridine- N)copper(II)], [Cu2(C6H6NO2)4-(C 6H7N)2], (III), the dinuclear CuII complex has a cage structure, with a Cu⋯Cu distance of 2.671 (1) Å. The magnetic -2J value for (III) is 343 cm-1 (H = -2JS1.S2).

AB - In the crystal structure of trans-dichlorobis(trigonelline-O,O′)copper(II) (trigonelline is N-methylpyridinium-3-carboxylate), [CuCl2(C7H7NO2)2], (I), the monomeric CuII complex has a distorted octahedral coordination. In the crystal structure of tetrakis(μ-trigonelline-O:O′)-bis[chlorocopper(II)] dichloride octahydrate, [Cu2Cl2-(C7H7NO2) 4]Cl2·8H2O, (II), the dinuclear CuII complex has a slightly elongated cage structure, with a Cu⋯Cu distance of 2.770 (1) Å. In the crystal structure of tetrakis[μ-(1-methylpyrrole-2-carboxylato)-O:O′]-bis[(3-methylpyridine- N)copper(II)], [Cu2(C6H6NO2)4-(C 6H7N)2], (III), the dinuclear CuII complex has a cage structure, with a Cu⋯Cu distance of 2.671 (1) Å. The magnetic -2J value for (III) is 343 cm-1 (H = -2JS1.S2).

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A monomeric and a dimeric copper(II) trigonelline adduct with chloride, and a dimeric copper(II) 1-methyl-2-pyrrolecarboxylate adduct with 3-methylpyridine

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