A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

Zhao Yang Li; Jing Wei Dai; Kevin J. Gagnon; Hong Ling Cai; Takashi Yamamoto; Yasuaki Einaga; Han Hua Zhao; Shinji Kanegawa; Osamu Sato; Kim R. Dunbar; Ren Gen Xiong

doi:10.1039/c3dt51554k

A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

Zhao Yang Li, Jing Wei Dai, Kevin J. Gagnon, Hong Ling Cai, Takashi Yamamoto, Yasuaki Einaga, Han Hua Zhao, Shinji Kanegawa, Osamu Sato, Kim R. Dunbar, Ren Gen Xiong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H₂O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mössbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.

Original language	English
Pages (from-to)	14685-14688
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	41
DOIs	https://doi.org/10.1039/c3dt51554k
Publication status	Published - 2013 Nov 7

ASJC Scopus subject areas

Inorganic Chemistry

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title = "A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies",

abstract = "The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, M{\"o}ssbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.",

author = "Li, {Zhao Yang} and Dai, {Jing Wei} and Gagnon, {Kevin J.} and Cai, {Hong Ling} and Takashi Yamamoto and Yasuaki Einaga and Zhao, {Han Hua} and Shinji Kanegawa and Osamu Sato and Dunbar, {Kim R.} and Xiong, {Ren Gen}",

year = "2013",

month = nov,

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doi = "10.1039/c3dt51554k",

language = "English",

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journal = "Dalton Transactions",

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T1 - A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

AU - Li, Zhao Yang

AU - Dai, Jing Wei

AU - Gagnon, Kevin J.

AU - Cai, Hong Ling

AU - Yamamoto, Takashi

AU - Einaga, Yasuaki

AU - Zhao, Han Hua

AU - Kanegawa, Shinji

AU - Sato, Osamu

AU - Dunbar, Kim R.

AU - Xiong, Ren Gen

PY - 2013/11/7

Y1 - 2013/11/7

N2 - The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mössbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.

AB - The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mössbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.

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DO - 10.1039/c3dt51554k

M3 - Article

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AN - SCOPUS:84885113900

SN - 1477-9226

VL - 42

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EP - 14688

JO - Dalton Transactions

JF - Dalton Transactions

IS - 41

ER -

A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

Abstract

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