A new chelation-assistance mode for a ruthenium-catalyzed silylation at the C-H bond in aromatic ring with hydrosilanes

Fumitoshi Kakiuchi, Kimitaka Igi, Mitsutaka Matsumoto, Tomoo Hayamizu, Naoto Chatani, Shinji Murai

Research output: Contribution to journalArticle

106 Citations (Scopus)

Abstract

Ruthenium-catalyzed reactions of aromatic compounds having an amino group or a heteroaromatic ring as a directing group with triethylsilane gave the corresponding ortho silylated products in good to excellent yields. In contrast to our previous results, in which the reactive substrates with π-conjugation between the hetero atom in the directing group and the carbon atom possessing the C-H bond to be cleaved were used, the present reaction proceeds in cases of substrates having no such π-conjugation.

Original languageEnglish
Pages (from-to)396-397
Number of pages2
JournalChemistry Letters
Issue number3
DOIs
Publication statusPublished - 2002 Mar 5
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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