A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling

Fumitoshi Kakiuchi, Mitsutaka Matsumoto, Motohiro Sonoda, Takahide Fukuyama, Naoto Chatani, Shinji Murai, Naoyuki Furukawa, Yoshio Seki

Research output: Contribution to journalArticle

58 Citations (Scopus)

Abstract

Heteroarylsilanes can be synthesized by the reaction of heteroaromatic compounds with triorganovinylsilanes with the aid of a Ru3(CO)12-catalyst. A variety of heteroaromatic compounds can be used in this C-H/SiR3 coupling. The coupling reaction was observed to take place at a position β to the directing carbonyl group, e.g., ketone, ester, and amide, in the case of heteroaromatic compounds.

Original languageEnglish
Pages (from-to)750-751
Number of pages2
JournalChemistry Letters
Issue number7
Publication statusPublished - 2000
Externally publishedYes

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Ruthenium
Carbon Monoxide
Ketones
Amides
Esters
Catalysts

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Kakiuchi, F., Matsumoto, M., Sonoda, M., Fukuyama, T., Chatani, N., Murai, S., ... Seki, Y. (2000). A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling. Chemistry Letters, (7), 750-751.

A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling. / Kakiuchi, Fumitoshi; Matsumoto, Mitsutaka; Sonoda, Motohiro; Fukuyama, Takahide; Chatani, Naoto; Murai, Shinji; Furukawa, Naoyuki; Seki, Yoshio.

In: Chemistry Letters, No. 7, 2000, p. 750-751.

Research output: Contribution to journalArticle

Kakiuchi, F, Matsumoto, M, Sonoda, M, Fukuyama, T, Chatani, N, Murai, S, Furukawa, N & Seki, Y 2000, 'A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling', Chemistry Letters, no. 7, pp. 750-751.
Kakiuchi F, Matsumoto M, Sonoda M, Fukuyama T, Chatani N, Murai S et al. A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling. Chemistry Letters. 2000;(7):750-751.
Kakiuchi, Fumitoshi ; Matsumoto, Mitsutaka ; Sonoda, Motohiro ; Fukuyama, Takahide ; Chatani, Naoto ; Murai, Shinji ; Furukawa, Naoyuki ; Seki, Yoshio. / A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling. In: Chemistry Letters. 2000 ; No. 7. pp. 750-751.
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