A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling

Fumitoshi Kakiuchi, Mitsutaka Matsumoto, Motohiro Sonoda, Takahide Fukuyama, Naoto Chatani, Shinji Murai, Naoyuki Furukawa, Yoshio Seki

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62 Citations (Scopus)

Abstract

Heteroarylsilanes can be synthesized by the reaction of heteroaromatic compounds with triorganovinylsilanes with the aid of a Ru3(CO)12-catalyst. A variety of heteroaromatic compounds can be used in this C-H/SiR3 coupling. The coupling reaction was observed to take place at a position β to the directing carbonyl group, e.g., ketone, ester, and amide, in the case of heteroaromatic compounds.

Original languageEnglish
Pages (from-to)750-751
Number of pages2
JournalChemistry Letters
Issue number7
DOIs
Publication statusPublished - 2000 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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    Kakiuchi, F., Matsumoto, M., Sonoda, M., Fukuyama, T., Chatani, N., Murai, S., Furukawa, N., & Seki, Y. (2000). A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling. Chemistry Letters, (7), 750-751. https://doi.org/10.1246/cl.2000.750