A novel adduct of TCNQ dianion with Schiff-base cobalt(III) complex in N-bonded coodination mode in Dmf solution [TCNQ=7,7,8,8-tetracyanoquinodimethane]

Yukako Ohashi, Yoshiki Oogo, Mikio Nakamura

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Formation of a stable novel adduct, [Co(III)(saloph)]2 TCNQ(-II), has been confirmed by analysis of the 1H NMR spectra of the N,N-dimethylformamide(dmf)-acetonitrile solution of LiTCNQ and [N,N1-o-phenylenebis(salicylideneaminato)] cobalt (II), denoted as [Co(II)(saloph)]. The time-resolved spectra of the UV-vis absorption of the LiTCNQ-[Co(II)(saloph)] solutions gave information concerning the formation process of the adduct.

Original languageEnglish
Pages (from-to)1187-1188
Number of pages2
JournalChemistry Letters
Issue number11
DOIs
Publication statusPublished - 1999

ASJC Scopus subject areas

  • Chemistry(all)

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