A redetermination of bis(N-methylethyl-enediamine-κ2/N, N′)bis(perchlorato-κO)-copper(II)

Takashiro Akitsu, Yasuaki Einaga

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

In the title compound, [Cu(ClO4)2(C3H 10N2)2], the Cu atom is located at a center of symmetry. Despite asymmetric introduction of TV-methyl groups into the ethylenediamine moieties, a second-order Jahn-Teller effect produces a typical semi-coordination trans-[CuN4(O2)] environment with long axial Cu - O bonds of 2.569 (2) Å. The Cu - N bond distances are 2.004 (2) and 2.057 (2) Å.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number11
DOIs
Publication statusPublished - 2003 Nov

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ethylenediamine
Jahn-Teller effect
Copper
copper
Atoms
symmetry
atoms
perchlorate

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

A redetermination of bis(N-methylethyl-enediamine-κ2/N, N′)bis(perchlorato-κO)-copper(II). / Akitsu, Takashiro; Einaga, Yasuaki.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 11, 11.2003.

Research output: Contribution to journal › Article

Akitsu, T & Einaga, Y 2003, 'A redetermination of bis(N-methylethyl-enediamine-κ2/N, N′)bis(perchlorato-κO)-copper(II)', Acta Crystallographica Section E: Structure Reports Online, vol. 59, no. 11. https://doi.org/10.1107/S160053680302213X
Akitsu T, Einaga Y. A redetermination of bis(N-methylethyl-enediamine-κ2/N, N′)bis(perchlorato-κO)-copper(II). Acta Crystallographica Section E: Structure Reports Online. 2003 Nov;59(11). https://doi.org/10.1107/S160053680302213X
Akitsu, Takashiro ; Einaga, Yasuaki. / A redetermination of bis(N-methylethyl-enediamine-κ2/N, N′)bis(perchlorato-κO)-copper(II). In: Acta Crystallographica Section E: Structure Reports Online. 2003 ; Vol. 59, No. 11.
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