TY - JOUR
T1 - A redetermination of bis(N-methylethyl-enediamine-κ2/N, N′)bis(perchlorato-κO)-copper(II)
AU - Akitsu, Takashiro
AU - Einaga, Yasuaki
PY - 2003/11/1
Y1 - 2003/11/1
N2 - In the title compound, [Cu(ClO4)2(C3H 10N2)2], the Cu atom is located at a center of symmetry. Despite asymmetric introduction of TV-methyl groups into the ethylenediamine moieties, a second-order Jahn-Teller effect produces a typical semi-coordination trans-[CuN4(O2)] environment with long axial Cu - O bonds of 2.569 (2) Å. The Cu - N bond distances are 2.004 (2) and 2.057 (2) Å.
AB - In the title compound, [Cu(ClO4)2(C3H 10N2)2], the Cu atom is located at a center of symmetry. Despite asymmetric introduction of TV-methyl groups into the ethylenediamine moieties, a second-order Jahn-Teller effect produces a typical semi-coordination trans-[CuN4(O2)] environment with long axial Cu - O bonds of 2.569 (2) Å. The Cu - N bond distances are 2.004 (2) and 2.057 (2) Å.
UR - http://www.scopus.com/inward/record.url?scp=2442632475&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=2442632475&partnerID=8YFLogxK
U2 - 10.1107/S160053680302213X
DO - 10.1107/S160053680302213X
M3 - Article
AN - SCOPUS:2442632475
VL - 59
SP - m991-m993
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 11
ER -