A redetermination of bis(N-methylethyl-enediamine-κ2/N, N′)bis(perchlorato-κO)-copper(II)

Takashiro Akitsu, Yasuaki Einaga

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

In the title compound, [Cu(ClO4)2(C3H 10N2)2], the Cu atom is located at a center of symmetry. Despite asymmetric introduction of TV-methyl groups into the ethylenediamine moieties, a second-order Jahn-Teller effect produces a typical semi-coordination trans-[CuN4(O2)] environment with long axial Cu - O bonds of 2.569 (2) Å. The Cu - N bond distances are 2.004 (2) and 2.057 (2) Å.

Original languageEnglish
Pages (from-to)m991-m993
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number11
DOIs
Publication statusPublished - 2003 Nov 1

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ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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