A spin-crossover cluster of iron(II) exhibiting a mixed-spin structure and synergy between spin transition and magnetic interaction

Da Yu Wu, Osamu Sato, Yasuaki Einaga, Chun Ying Duan

Research output: Contribution to journalArticlepeer-review

156 Citations (Scopus)

Abstract

How low can you go? An Fell4 square was prepared by self-assembly and exhibits both thermally induced and photoinduced spin crossover from a system with four high-spin (HS) centers to one with two high-spin and two low-spin (LS) centres. The spin-crossover sites are located on the same side of the square, and the spin transition and magnetic interactions (see picture) are synergistically coupled.

Original languageEnglish
Pages (from-to)1475-1478
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number8
DOIs
Publication statusPublished - 2009 Feb 9

Keywords

  • Cluster compounds
  • Iron
  • Magnetic properties
  • Spin crossover

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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