A synthetic study of (-)-dihydroedulan II and related compounds

Takeshi Sugai, Tomoki Yokochi, Naoyuki Watanabe, Hiromichi Ohta

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

(-)-Dihydroedulan II and related compounds were synthesized from (2R,1′RS)-dihydro-α-ionol, which was prepared by lipase-catalyzed enantioselective transesterification of the corresponding diastereomeric mixture as the key-step. Fungal allylic oxidation of (-)-dihydroedulan II worked well to afford a corresponding alcohol as well as (+)-dihydroedulan-8-one.

Original languageEnglish
Pages (from-to)7227-7236
Number of pages10
JournalTetrahedron
Volume47
Issue number35
DOIs
Publication statusPublished - 1991 Aug 26

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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