Adsorption-induced stability reversal of photochromic diarylethene on metal surfaces

Tomoko Shimizu, Jaehoon Jung, Hiroshi Imada, Yousoo Kim

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A scanning tunneling microscopy study of a photochromic diarylethene adsorbed on Au and Cu reveals the reversal of thermodynamic stability between its two isomers compared to the gas phase, in solution, and its single crystal, which could result from the molecule-substrate interaction such as charge transfer and hybridization.

Original languageEnglish
Pages (from-to)8710-8712
Number of pages3
JournalChemical Communications
Volume49
Issue number77
DOIs
Publication statusPublished - 2013 Oct 7
Externally publishedYes

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Scanning tunneling microscopy
Isomers
Charge transfer
Thermodynamic stability
Gases
Metals
Single crystals
Adsorption
Molecules
Substrates

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Adsorption-induced stability reversal of photochromic diarylethene on metal surfaces. / Shimizu, Tomoko; Jung, Jaehoon; Imada, Hiroshi; Kim, Yousoo.

In: Chemical Communications, Vol. 49, No. 77, 07.10.2013, p. 8710-8712.

Research output: Contribution to journalArticle

Shimizu, Tomoko ; Jung, Jaehoon ; Imada, Hiroshi ; Kim, Yousoo. / Adsorption-induced stability reversal of photochromic diarylethene on metal surfaces. In: Chemical Communications. 2013 ; Vol. 49, No. 77. pp. 8710-8712.
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