An abrupt spin transition based on short S⋯S contacts in a novel Fe(II) complex whose ligand contains a 1,3-dithiole ring

Kazuyuki Takahashi, Tomoko Kawakami, Zhong Ze Gu, Yasuaki Einaga, Akira Fujishima, Osamu Sato

Research output: Contribution to journalArticlepeer-review

33 Citations (Scopus)

Abstract

The first preparation of an Fe(II) spin-crossover complex including a 1,3-dithiole ligand is reported. Crystal analyses of both the low- and the high-temperature phases reveal that short S⋯S contacts play a key role in an abrupt spin transition.

Original languageEnglish
Pages (from-to)2374-2375
Number of pages2
JournalChemical Communications
Volume3
Issue number18
DOIs
Publication statusPublished - 2003 Jan 1

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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