An equation of state for 1,1,1-trifluoroethane (R-143a)

J. Li, R. Tillner-Roth, H. Sato, K. Watanabe

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37 Citations (Scopus)

Abstract

A fundamental equation of state has been developed for 1,1,1-trifluoroethane (R-143a) using the dimensionless Helmholtz energy. The experimental thermodynamic property data, which cover temperatures from the triple point (161 K) to 433 K and pressures up to 35 M Pa, are used to develop the present equation. These data are represented by the present equation within their reported experimental uncertainties: ±0.1% in density for both vapor and liquid phase P-ρ- T data, ±1% in isochoric specific heat capacities, and ±0.02% in the vapor phase speed-of-sound data. The extended range of validity of the present model covers temperatures from 160 to 650 K and pressures up to 50 M Pa as verified by the thermodynamic behavior of the isobaric heat-capacity values over the entire fluid phase.

Original languageEnglish
Pages (from-to)1639-1651
Number of pages13
JournalInternational Journal of Thermophysics
Volume20
Issue number6
Publication statusPublished - 1999
Externally publishedYes

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Keywords

  • 1,1,1-trifluoroethane
  • Alternative refrigerant
  • Equation of state
  • Helmholtz energy
  • R-143a

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Mechanics of Materials
  • Computational Mechanics
  • Fluid Flow and Transfer Processes
  • Physics and Astronomy (miscellaneous)
  • Condensed Matter Physics

Cite this

Li, J., Tillner-Roth, R., Sato, H., & Watanabe, K. (1999). An equation of state for 1,1,1-trifluoroethane (R-143a). International Journal of Thermophysics, 20(6), 1639-1651.