An expeditious and enantioselective entry to the ABC ring of the quassinoid skeleton

Tony Kung Ming Shing, Ying Tang, John F. Malone

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The tricycle (5) with two trans-fused angular methyl groups is constructed from tiglic aldehyde and (S)-carvone involving a stereocontrolled aldol reaction and an endo-selective intramolecular Diels-Alder (IMDA) reaction; the stereochemistry was established by an X-ray study.

Original languageEnglish
Pages (from-to)1294-1295
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
DOIs
Publication statusPublished - 1989 Jan 1
Externally publishedYes

Fingerprint

Quassins
Stereochemistry
Cycloaddition Reaction
Aldehydes
Skeleton
X-Rays
X rays
carvone
3-hydroxybutanal

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

An expeditious and enantioselective entry to the ABC ring of the quassinoid skeleton. / Shing, Tony Kung Ming; Tang, Ying; Malone, John F.

In: Journal of the Chemical Society, Chemical Communications, No. 17, 01.01.1989, p. 1294-1295.

Research output: Contribution to journalArticle

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