An expeditious and enantioselective entry to the ABC ring of the quassinoid skeleton

Tony K.M. Shing; Ying Tang; John F. Malone

doi:10.1039/C39890001294

An expeditious and enantioselective entry to the ABC ring of the quassinoid skeleton

Tony K.M. Shing, Ying Tang, John F. Malone

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The tricycle (5) with two trans-fused angular methyl groups is constructed from tiglic aldehyde and (S)-carvone involving a stereocontrolled aldol reaction and an endo-selective intramolecular Diels-Alder (IMDA) reaction; the stereochemistry was established by an X-ray study.

Original language	English
Pages (from-to)	1294-1295
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/C39890001294
Publication status	Published - 1989 Jan 1

ASJC Scopus subject areas

Molecular Medicine

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abstract = "The tricycle (5) with two trans-fused angular methyl groups is constructed from tiglic aldehyde and (S)-carvone involving a stereocontrolled aldol reaction and an endo-selective intramolecular Diels-Alder (IMDA) reaction; the stereochemistry was established by an X-ray study.",

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AB - The tricycle (5) with two trans-fused angular methyl groups is constructed from tiglic aldehyde and (S)-carvone involving a stereocontrolled aldol reaction and an endo-selective intramolecular Diels-Alder (IMDA) reaction; the stereochemistry was established by an X-ray study.

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An expeditious and enantioselective entry to the ABC ring of the quassinoid skeleton

Abstract

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