The tricycle (5) with two trans-fused angular methyl groups is constructed from tiglic aldehyde and (S)-carvone involving a stereocontrolled aldol reaction and an endo-selective intramolecular Diels-Alder (IMDA) reaction; the stereochemistry was established by an X-ray study.
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|Publication status||Published - 1989 Jan 1|
ASJC Scopus subject areas
- Molecular Medicine