Anisotropy of dodecahedral water cages for guest gas occupancy in semiclathrate hydrates

Daisuke Yuhara, Kenji Yasuoka, Satoshi Takeya, Sanehiro Muromachi

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Anisotropic dodecahedral (D) water cages found in semiclathrate hydrates have unique gas selectivity due to their varied shapes. Herein, the D cages incorporating ideally isotropic rare gases, i.e., Xe, Kr and Ar, were characterized by crystal structure analyses. Stabilization mechanisms of the semiclathrate hydrates by the D cages are discussed.

Original languageEnglish
Pages (from-to)10150-10153
Number of pages4
JournalChemical Communications
Volume55
Issue number68
DOIs
Publication statusPublished - 2019 Jan 1

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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