Anisotropy of synthetic diamond in catalytic etching using iron powder

Junsha Wang, Long Wan, Jing Chen, Jiwang Yan

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

This paper demonstrated a novel technique for catalytic etching of synthetic diamond crystallites using iron (Fe) powder without flowing gas. The effect of temperature on the etching behaviour on different crystal planes of diamond was investigated. The surface morphology and surface roughness of the processed diamond were examined by scanning electron microscope (SEM) and laser-probe surface profiling. In addition, the material composition of the Fe-treated diamond was characterized using micro-Raman spectroscopy and the distribution of chemical elements and structural changes on Fe-loaded diamond surfaces were analyzed by energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD), respectively. Results showed that at the same temperature the {1 0 0} plane was etched faster than the {1 1 1} plane, and that the etching rate of both {1 0 0} and {1 1 1} plane increased with temperature. The etch pits on {1 0 0} plane were reversed pyramid with flat {1 1 1} walls, while the etch holes on {1 1 1} plane were characterized with flat bottom. It was also demonstrated that graphitization of diamond and subsequent carbon diffusion in molten iron were two main factors resulting in the removal of carbon from the diamond surface.

Original languageEnglish
Pages (from-to)388-393
Number of pages6
JournalApplied Surface Science
Volume346
DOIs
Publication statusPublished - 2015 Aug 15

Fingerprint

Synthetic diamonds
Iron powder
Diamond
Etching
Diamonds
Anisotropy
Carbon
Iron
Graphitization
Crystallites
Chemical elements
Powders
Temperature
Surface morphology
Raman spectroscopy
Molten materials
Energy dispersive spectroscopy
Electron microscopes
Gases
Surface roughness

Keywords

  • Catalytic etching
  • Crystal plane
  • Iron
  • Synthetic diamond crystallite
  • Temperature

ASJC Scopus subject areas

  • Surfaces, Coatings and Films

Cite this

Anisotropy of synthetic diamond in catalytic etching using iron powder. / Wang, Junsha; Wan, Long; Chen, Jing; Yan, Jiwang.

In: Applied Surface Science, Vol. 346, 15.08.2015, p. 388-393.

Research output: Contribution to journalArticle

Wang, Junsha ; Wan, Long ; Chen, Jing ; Yan, Jiwang. / Anisotropy of synthetic diamond in catalytic etching using iron powder. In: Applied Surface Science. 2015 ; Vol. 346. pp. 388-393.
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