Anodic oxidation on a boron-doped diamond electrode mediated by methoxy radicals

Takenori Sumi, Tsuyoshi Saitoh, Keisuke Natsui, Takashi Yamamoto, Mahito Atobe, Yasuaki Einaga, Shigeru Nishiyama

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

Direct evidence: The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron-doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarinA, was accomplished by the BDD-mediated anodic oxidation protocol (see picture).

Original languageEnglish
Pages (from-to)5443-5446
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number22
DOIs
Publication statusPublished - 2012 May 29

Fingerprint

Diamond
Boron
Anodic oxidation
Diamonds
Lignans
Electrodes
Paramagnetic resonance
Spectroscopy

Keywords

  • boron-doped diamond electrode
  • electrochemistry
  • electrosynthesis
  • radicals

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Anodic oxidation on a boron-doped diamond electrode mediated by methoxy radicals. / Sumi, Takenori; Saitoh, Tsuyoshi; Natsui, Keisuke; Yamamoto, Takashi; Atobe, Mahito; Einaga, Yasuaki; Nishiyama, Shigeru.

In: Angewandte Chemie - International Edition, Vol. 51, No. 22, 29.05.2012, p. 5443-5446.

Research output: Contribution to journalArticle

Sumi, Takenori ; Saitoh, Tsuyoshi ; Natsui, Keisuke ; Yamamoto, Takashi ; Atobe, Mahito ; Einaga, Yasuaki ; Nishiyama, Shigeru. / Anodic oxidation on a boron-doped diamond electrode mediated by methoxy radicals. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 22. pp. 5443-5446.
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