Anodic oxidation on a boron-doped diamond electrode mediated by methoxy radicals

Takenori Sumi, Tsuyoshi Saitoh, Keisuke Natsui, Takashi Yamamoto, Mahito Atobe, Yasuaki Einaga, Shigeru Nishiyama

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

Direct evidence: The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron-doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarinA, was accomplished by the BDD-mediated anodic oxidation protocol (see picture).

Original languageEnglish
Pages (from-to)5443-5446
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number22
DOIs
Publication statusPublished - 2012 May 29

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Keywords

  • boron-doped diamond electrode
  • electrochemistry
  • electrosynthesis
  • radicals

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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