Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries

Takeshi Shimizu, Koji Yamamoto, Palash Pandit, Hirofumi Yoshikawa, Shuhei Higashibayashi

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Hydrazine-embedded heterocyclic compounds with dimeric dimethylacridine (1b), carbazole (2b), and phenothiazine (3b) skeletons were applied to cathode active materials of rechargeable lithium organic batteries, and the performance of the batteries was evaluated. The charge/discharge curves exhibited clear plateaus in the high voltage range of 3.3-3.7 V. The capacities of the plateau regions were comparable to the calculated capacities corresponding to the one-electron redox of the molecules. The amount of the active compound 3b could be increased up to 30 wt% in the electrode composite, and fast charge/discharge performance was also observed.

Original languageEnglish
Article number579
JournalScientific Reports
Volume8
Issue number1
DOIs
Publication statusPublished - 2018 Dec 1

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hydrazine
Heterocyclic Compounds
Lithium
Cathodes
Electrodes
Molecules
Electrons
Composite materials
Electric potential
carbazole
Oxidation-Reduction
phenothiazine

ASJC Scopus subject areas

  • General

Cite this

Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries. / Shimizu, Takeshi; Yamamoto, Koji; Pandit, Palash; Yoshikawa, Hirofumi; Higashibayashi, Shuhei.

In: Scientific Reports, Vol. 8, No. 1, 579, 01.12.2018.

Research output: Contribution to journalArticle

Shimizu, Takeshi ; Yamamoto, Koji ; Pandit, Palash ; Yoshikawa, Hirofumi ; Higashibayashi, Shuhei. / Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries. In: Scientific Reports. 2018 ; Vol. 8, No. 1.
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