Arylation of aryllithiums with: S-arylphenothiazinium ions for biaryl synthesis

Tatsuya Morofuji; Tatsuki Yoshida; Ryosuke Tsutsumi; Masahiro Yamanaka; Naokazu Kano

doi:10.1039/d0cc05830k

Arylation of aryllithiums with: S-arylphenothiazinium ions for biaryl synthesis

Tatsuya Morofuji, Tatsuki Yoshida, Ryosuke Tsutsumi, Masahiro Yamanaka, Naokazu Kano

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Aryllithiums are one of the most common and important aryl nucleophiles; nevertheless, methods for arylation of aryllithums to produce biaryls have been limited. Herein, we report arylation of aryllithiums with S-arylphenothiazinium ions through selective ligand coupling of intermediary sulfuranes. Various unsymmetrical biaryls could be obtained without transition-metal catalysis. This journal is

Original language	English
Pages (from-to)	13995-13998
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	90
DOIs	https://doi.org/10.1039/d0cc05830k
Publication status	Published - 2020 Nov 21
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Aryllithiums are one of the most common and important aryl nucleophiles; nevertheless, methods for arylation of aryllithums to produce biaryls have been limited. Herein, we report arylation of aryllithiums with S-arylphenothiazinium ions through selective ligand coupling of intermediary sulfuranes. Various unsymmetrical biaryls could be obtained without transition-metal catalysis. This journal is ",

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AU - Morofuji, Tatsuya

AU - Yoshida, Tatsuki

AU - Tsutsumi, Ryosuke

AU - Yamanaka, Masahiro

AU - Kano, Naokazu

N1 - Funding Information: This research was partially supported by the MEXT-supported program for the Strategic Research Foundation at Private Universities, and the Society of Iodine Science. DFT calculations were performed using Research Center for Computational Science, Okazaki, Japan. Publisher Copyright: © The Royal Society of Chemistry.

PY - 2020/11/21

Y1 - 2020/11/21

N2 - Aryllithiums are one of the most common and important aryl nucleophiles; nevertheless, methods for arylation of aryllithums to produce biaryls have been limited. Herein, we report arylation of aryllithiums with S-arylphenothiazinium ions through selective ligand coupling of intermediary sulfuranes. Various unsymmetrical biaryls could be obtained without transition-metal catalysis. This journal is

AB - Aryllithiums are one of the most common and important aryl nucleophiles; nevertheless, methods for arylation of aryllithums to produce biaryls have been limited. Herein, we report arylation of aryllithiums with S-arylphenothiazinium ions through selective ligand coupling of intermediary sulfuranes. Various unsymmetrical biaryls could be obtained without transition-metal catalysis. This journal is

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Arylation of aryllithiums with: S-arylphenothiazinium ions for biaryl synthesis

Abstract

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