Barriers to inversion of nonplanar ferric porphyrin radical cations: Comparison with the corresponding neutral complexes

Mikio Nakamura; Tatsuya Yamaguchi; Yoshiki Ohgo

doi:10.1021/ic990139e

Barriers to inversion of nonplanar ferric porphyrin radical cations: Comparison with the corresponding neutral complexes

Mikio Nakamura, Tatsuya Yamaguchi, Yoshiki Ohgo

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17 Citations (Scopus)

Abstract

Barriers to inversion of the highly deformed porphyrin rings in two ferric porphyrin radical cations, [Fe(OMTPP)Cl]SbCl₆ and [Fe(OETPP)Cl]SbCl₁ where OMTPP and OETPP are dianions of 2,3,7,8,12,13,17,18-octamethyl-and 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin, respectively, have been determined by the dynamic NMR method.

Original language	English
Pages (from-to)	3126-3131
Number of pages	6
Journal	Inorganic Chemistry
Volume	38
Issue number	13
DOIs	https://doi.org/10.1021/ic990139e
Publication status	Published - 1999
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic990139e

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abstract = "Barriers to inversion of the highly deformed porphyrin rings in two ferric porphyrin radical cations, [Fe(OMTPP)Cl]SbCl6 and [Fe(OETPP)Cl]SbCl1 where OMTPP and OETPP are dianions of 2,3,7,8,12,13,17,18-octamethyl-and 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin, respectively, have been determined by the dynamic NMR method.",

author = "Mikio Nakamura and Tatsuya Yamaguchi and Yoshiki Ohgo",

year = "1999",

doi = "10.1021/ic990139e",

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journal = "Inorganic Chemistry",

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T1 - Barriers to inversion of nonplanar ferric porphyrin radical cations

T2 - Comparison with the corresponding neutral complexes

AU - Nakamura, Mikio

AU - Yamaguchi, Tatsuya

AU - Ohgo, Yoshiki

PY - 1999

Y1 - 1999

N2 - Barriers to inversion of the highly deformed porphyrin rings in two ferric porphyrin radical cations, [Fe(OMTPP)Cl]SbCl6 and [Fe(OETPP)Cl]SbCl1 where OMTPP and OETPP are dianions of 2,3,7,8,12,13,17,18-octamethyl-and 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin, respectively, have been determined by the dynamic NMR method.

AB - Barriers to inversion of the highly deformed porphyrin rings in two ferric porphyrin radical cations, [Fe(OMTPP)Cl]SbCl6 and [Fe(OETPP)Cl]SbCl1 where OMTPP and OETPP are dianions of 2,3,7,8,12,13,17,18-octamethyl-and 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin, respectively, have been determined by the dynamic NMR method.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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Barriers to inversion of nonplanar ferric porphyrin radical cations: Comparison with the corresponding neutral complexes

Abstract

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