Abstract
Barriers to inversion of the highly deformed porphyrin rings in two ferric porphyrin radical cations, [Fe(OMTPP)Cl]SbCl6 and [Fe(OETPP)Cl]SbCl1 where OMTPP and OETPP are dianions of 2,3,7,8,12,13,17,18-octamethyl-and 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin, respectively, have been determined by the dynamic NMR method.
| Original language | English |
|---|---|
| Pages (from-to) | 3126-3131 |
| Number of pages | 6 |
| Journal | Inorganic Chemistry |
| Volume | 38 |
| Issue number | 13 |
| Publication status | Published - 1999 Dec 1 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
Cite this
Nakamura, M., Yamaguchi, T., & Ohgo, Y. (1999). Barriers to inversion of nonplanar ferric porphyrin radical cations: Comparison with the corresponding neutral complexes. Inorganic Chemistry, 38(13), 3126-3131.