Barriers to inversion of nonplanar ferric porphyrin radical cations: Comparison with the corresponding neutral complexes

Mikio Nakamura, Tatsuya Yamaguchi, Yoshiki Ohgo

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Barriers to inversion of the highly deformed porphyrin rings in two ferric porphyrin radical cations, [Fe(OMTPP)Cl]SbCl6 and [Fe(OETPP)Cl]SbCl1 where OMTPP and OETPP are dianions of 2,3,7,8,12,13,17,18-octamethyl-and 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin, respectively, have been determined by the dynamic NMR method.

Original languageEnglish
Pages (from-to)3126-3131
Number of pages6
JournalInorganic Chemistry
Issue number13
Publication statusPublished - 1999 Dec 1


ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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