TY - JOUR
T1 - Barriers to inversion of nonplanar ferric porphyrin radical cations
T2 - Comparison with the corresponding neutral complexes
AU - Nakamura, Mikio
AU - Yamaguchi, Tatsuya
AU - Ohgo, Yoshiki
PY - 1999/1/1
Y1 - 1999/1/1
N2 - Barriers to inversion of the highly deformed porphyrin rings in two ferric porphyrin radical cations, [Fe(OMTPP)Cl]SbCl6 and [Fe(OETPP)Cl]SbCl1 where OMTPP and OETPP are dianions of 2,3,7,8,12,13,17,18-octamethyl-and 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin, respectively, have been determined by the dynamic NMR method.
AB - Barriers to inversion of the highly deformed porphyrin rings in two ferric porphyrin radical cations, [Fe(OMTPP)Cl]SbCl6 and [Fe(OETPP)Cl]SbCl1 where OMTPP and OETPP are dianions of 2,3,7,8,12,13,17,18-octamethyl-and 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin, respectively, have been determined by the dynamic NMR method.
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U2 - 10.1021/ic990139e
DO - 10.1021/ic990139e
M3 - Article
AN - SCOPUS:0000241982
VL - 38
SP - 3126
EP - 3131
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 13
ER -