Barriers to inversion of the highly deformed porphyrin rings in two ferric porphyrin radical cations, [Fe(OMTPP)Cl]SbCl6 and [Fe(OETPP)Cl]SbCl1 where OMTPP and OETPP are dianions of 2,3,7,8,12,13,17,18-octamethyl-and 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin, respectively, have been determined by the dynamic NMR method.
|Number of pages||6|
|Publication status||Published - 1999 Dec 1|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry