Barriers to inversion of nonplanar ferric porphyrin radical cations

Comparison with the corresponding neutral complexes

Mikio Nakamura, Tatsuya Yamaguchi, Yoshiki Ohgo

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Barriers to inversion of the highly deformed porphyrin rings in two ferric porphyrin radical cations, [Fe(OMTPP)Cl]SbCl6 and [Fe(OETPP)Cl]SbCl1 where OMTPP and OETPP are dianions of 2,3,7,8,12,13,17,18-octamethyl-and 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin, respectively, have been determined by the dynamic NMR method.

Original languageEnglish
Pages (from-to)3126-3131
Number of pages6
JournalInorganic Chemistry
Volume38
Issue number13
Publication statusPublished - 1999

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Porphyrins
porphyrins
Cations
inversions
cations
Nuclear magnetic resonance
nuclear magnetic resonance
rings
5,10,15,20-tetraphenylporphyrin

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Barriers to inversion of nonplanar ferric porphyrin radical cations : Comparison with the corresponding neutral complexes. / Nakamura, Mikio; Yamaguchi, Tatsuya; Ohgo, Yoshiki.

In: Inorganic Chemistry, Vol. 38, No. 13, 1999, p. 3126-3131.

Research output: Contribution to journalArticle

Nakamura, Mikio ; Yamaguchi, Tatsuya ; Ohgo, Yoshiki. / Barriers to inversion of nonplanar ferric porphyrin radical cations : Comparison with the corresponding neutral complexes. In: Inorganic Chemistry. 1999 ; Vol. 38, No. 13. pp. 3126-3131.
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