Bis(1-methylimidazole) complex of iron(III) oxypyriporphyrin adopting an intermediate-spin state

Hajime Eguchi; Yoshiki Ohgo; Akira Ikezaki; Saburo Neya; Mikio Nakamura

doi:10.1246/cl.2008.768

Bis(1-methylimidazole) complex of iron(III) oxypyriporphyrin adopting an intermediate-spin state

Hajime Eguchi, Yoshiki Ohgo, Akira Ikezaki, Saburo Neya, Mikio Nakamura

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Bis(1-methylimidazole) complex of iron(III) oxypyriporphyrin adopts an essentially pure intermediate-spin (S = 3/2) state at 298 K, which is the first example of the iron(III) porphyrinoid adopting the S = 3/2 in spite of the bis-coordination of imidazole ligand.

Original language	English
Pages (from-to)	768-769
Number of pages	2
Journal	Chemistry Letters
Volume	37
Issue number	7
DOIs	https://doi.org/10.1246/cl.2008.768
Publication status	Published - 2008 Jul 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2008.768

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abstract = "Bis(1-methylimidazole) complex of iron(III) oxypyriporphyrin adopts an essentially pure intermediate-spin (S = 3/2) state at 298 K, which is the first example of the iron(III) porphyrinoid adopting the S = 3/2 in spite of the bis-coordination of imidazole ligand.",

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AU - Eguchi, Hajime

AU - Ohgo, Yoshiki

AU - Ikezaki, Akira

AU - Neya, Saburo

AU - Nakamura, Mikio

PY - 2008/7/5

Y1 - 2008/7/5

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AB - Bis(1-methylimidazole) complex of iron(III) oxypyriporphyrin adopts an essentially pure intermediate-spin (S = 3/2) state at 298 K, which is the first example of the iron(III) porphyrinoid adopting the S = 3/2 in spite of the bis-coordination of imidazole ligand.

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Bis(1-methylimidazole) complex of iron(III) oxypyriporphyrin adopting an intermediate-spin state

Abstract

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