Bis[2-(phenethyliminomethyl)phenolato-κ2N,O]-copper(II)

Takashiro Akitsu; Yasuaki Einaga

doi:10.1107/S1600536804023736

Bis[2-(phenethyliminomethyl)phenolato-κ²N,O]-copper(II)

Takashiro Akitsu, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The title compound, [Cu(C₁₅H₁₄NO)₂], adopts a stepped conformation and displays a square-planar trans-[CuN ₂O₂] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the Cu-N and Cu-O bond distances are 2.013 (2) and 1.893 (2) Å, respectively, while for the other molecule, these distances are 2.008 (2) and 1.896 (2) A. The extended conformation of the phenethylimine pendant groups results in crystal packing formed by weakly aggregated planar molecules.

Original language	English
Pages (from-to)	m1555-m1557
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	11
DOIs	https://doi.org/10.1107/S1600536804023736
Publication status	Published - 2004 Nov

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536804023736

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title = "Bis[2-(phenethyliminomethyl)phenolato-κ2N,O]-copper(II)",

abstract = "The title compound, [Cu(C15H14NO)2], adopts a stepped conformation and displays a square-planar trans-[CuN 2O2] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the Cu-N and Cu-O bond distances are 2.013 (2) and 1.893 (2) {\AA}, respectively, while for the other molecule, these distances are 2.008 (2) and 1.896 (2) A. The extended conformation of the phenethylimine pendant groups results in crystal packing formed by weakly aggregated planar molecules.",

author = "Takashiro Akitsu and Yasuaki Einaga",

year = "2004",

month = nov,

doi = "10.1107/S1600536804023736",

language = "English",

volume = "60",

pages = "m1555--m1557",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "11",

}

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T1 - Bis[2-(phenethyliminomethyl)phenolato-κ2N,O]-copper(II)

AU - Akitsu, Takashiro

AU - Einaga, Yasuaki

PY - 2004/11

Y1 - 2004/11

N2 - The title compound, [Cu(C15H14NO)2], adopts a stepped conformation and displays a square-planar trans-[CuN 2O2] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the Cu-N and Cu-O bond distances are 2.013 (2) and 1.893 (2) Å, respectively, while for the other molecule, these distances are 2.008 (2) and 1.896 (2) A. The extended conformation of the phenethylimine pendant groups results in crystal packing formed by weakly aggregated planar molecules.

AB - The title compound, [Cu(C15H14NO)2], adopts a stepped conformation and displays a square-planar trans-[CuN 2O2] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the Cu-N and Cu-O bond distances are 2.013 (2) and 1.893 (2) Å, respectively, while for the other molecule, these distances are 2.008 (2) and 1.896 (2) A. The extended conformation of the phenethylimine pendant groups results in crystal packing formed by weakly aggregated planar molecules.

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M3 - Article

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SN - 1600-5368

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Bis[2-(phenethyliminomethyl)phenolato-κ²N,O]-copper(II)

Abstract

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