Bis[2-(phenethyliminomethyl)phenolato-κ2N,O]-copper(II)

Takashiro Akitsu, Yasuaki Einaga

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The title compound, [Cu(C15H14NO)2], adopts a stepped conformation and displays a square-planar trans-[CuN 2O2] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the Cu-N and Cu-O bond distances are 2.013 (2) and 1.893 (2) Å, respectively, while for the other molecule, these distances are 2.008 (2) and 1.896 (2) A. The extended conformation of the phenethylimine pendant groups results in crystal packing formed by weakly aggregated planar molecules.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number11
DOIs
Publication statusPublished - 2004 Nov

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Copper
copper
Molecules
Conformations
molecules
Atoms
Crystals
Geometry
symmetry
geometry
crystals
atoms

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Bis[2-(phenethyliminomethyl)phenolato-κ2N,O]-copper(II). / Akitsu, Takashiro; Einaga, Yasuaki.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 11, 11.2004.

Research output: Contribution to journalArticle

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AB - The title compound, [Cu(C15H14NO)2], adopts a stepped conformation and displays a square-planar trans-[CuN 2O2] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the Cu-N and Cu-O bond distances are 2.013 (2) and 1.893 (2) Å, respectively, while for the other molecule, these distances are 2.008 (2) and 1.896 (2) A. The extended conformation of the phenethylimine pendant groups results in crystal packing formed by weakly aggregated planar molecules.

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