Bis(acetone-κO)bis(N,N′-dimethyl ethylenediamine- κ2N,N′)copper(II) diperchlorate

Takashiro Akitsu, Yasuaki Einaga

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Abstract

The crystal structure of the bis(acetone-κO)bis(N,N′- dimethylethylenediamine-κ2N,N′)copper(II) diperchorate was investigated. It was found that an elongated octahedral trans-[CuN 4O2] coordination geometry was adopted by the complex compound. Two ligands, at the axial sites having O-M-O axial acetone bonds, were also observed in the crystal structure of the metal complex. The results show that the bond length for inplane Cu-N is 2.041(3) Å and that for axial Cu-O is 2.507 (5) Å.

Original languageEnglish
Pages (from-to)m162-m164
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume60
Issue number4
DOIs
Publication statusPublished - 2004 Apr 1

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ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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