Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II)

Takashiro Akitsu; Yasuaki Einaga

doi:10.1107/S1600536804001461

Bis(N,N-dimethylethylenediamine-k²N,N′)-bis(perchlorato- kO)copper(II)

Takashiro Akitsu, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

In the title compound, [Cu(ClO₄)₂(C₄H ₁₂N₂)₂], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN₄O₂] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) Å, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) Å.

Original language	English
Pages (from-to)	m234-m236
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	2
DOIs	https://doi.org/10.1107/S1600536804001461
Publication status	Published - 2004 Feb 1

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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Akitsu, T., & Einaga, Y. (2004). Bis(N,N-dimethylethylenediamine-k²N,N′)-bis(perchlorato- kO)copper(II). Acta Crystallographica Section E: Structure Reports Online, 60(2), m234-m236. https://doi.org/10.1107/S1600536804001461

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title = "Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II)",

abstract = "In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) {\AA}, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) {\AA}.",

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N2 - In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) Å, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) Å.

AB - In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) Å, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) Å.

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