Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II)

Takashiro Akitsu; Yasuaki Einaga

doi:10.1107/S1600536804001461

Bis(N,N-dimethylethylenediamine-k²N,N′)-bis(perchlorato- kO)copper(II)

Takashiro Akitsu, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

In the title compound, [Cu(ClO₄)₂(C₄H ₁₂N₂)₂], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN₄O₂] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) Å, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) Å.

Original language	English
Pages (from-to)	m234-m236
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	2
DOIs	https://doi.org/10.1107/S1600536804001461
Publication status	Published - 2004 Feb 1

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II)",

abstract = "In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) {\AA}, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) {\AA}.",

author = "Takashiro Akitsu and Yasuaki Einaga",

year = "2004",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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T1 - Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II)

AU - Akitsu, Takashiro

AU - Einaga, Yasuaki

PY - 2004/2/1

Y1 - 2004/2/1

N2 - In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) Å, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) Å.

AB - In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) Å, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) Å.

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