Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II)

Takashiro Akitsu, Yasuaki Einaga

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) Å, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) Å.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number2
DOIs
Publication statusPublished - 2004 Feb

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Jahn-Teller effect
Bond length
Copper
copper
symmetry
geometry
atoms
Atoms
Geometry
dimethylethylenediamine
perchlorate

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II). / Akitsu, Takashiro; Einaga, Yasuaki.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 2, 02.2004.

Research output: Contribution to journal › Article

Akitsu, T & Einaga, Y 2004, 'Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II)', Acta Crystallographica Section E: Structure Reports Online, vol. 60, no. 2. https://doi.org/10.1107/S1600536804001461
Akitsu T, Einaga Y. Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II). Acta Crystallographica Section E: Structure Reports Online. 2004 Feb;60(2). https://doi.org/10.1107/S1600536804001461
Akitsu, Takashiro ; Einaga, Yasuaki. / Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II). In: Acta Crystallographica Section E: Structure Reports Online. 2004 ; Vol. 60, No. 2.
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