Bis[(R)-3,5-dichloro-N-(1-phenylethyl)salicylideneaminato-k 2N,O]-copper(ll) and bis[(R)-3-ethoxy-N-(1-phenylethyl) salicylideneaminato-K2N,O]copper(ll)

Takashiro Akitsu; Yasuaki Einaga

doi:10.1107/S0108270104026575

Bis[(R)-3,5-dichloro-N-(1-phenylethyl)salicylideneaminato-k ²N,O]-copper(ll) and bis[(R)-3-ethoxy-N-(1-phenylethyl) salicylideneaminato-K²N,O]copper(ll)

Takashiro Akitsu, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

The crystal structure of bis[(R)-3,5-dichloro-N-(1-phenyl-ethyl) salicylideneaminato- κ²N, O]-copper(II) and bis[(R)-3-ethoxy-N-(1-phenylethyl)salicylideneaminato-κ²N, O] copper(II) was investigated. The complexes adopt a compressed tetrahedral trans-[CuN₂O₂] coordination geometry. The complexes also differ from one another with respect to the 1-phenylethylamine moieties and the direction of the benzene rings. The structural change was found to be irreversible for both the complexes, though there are no intermolecular hydrogen bonds in the crystals.

Original language	English
Pages (from-to)	m640-m642
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	60
Issue number	12
DOIs	https://doi.org/10.1107/S0108270104026575
Publication status	Published - 2004 Dec

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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Bis[(R)-3,5-dichloro-N-(1-phenylethyl)salicylideneaminato-k ²N,O]-copper(ll) and bis[(R)-3-ethoxy-N-(1-phenylethyl) salicylideneaminato-K²N,O]copper(ll). / Akitsu, Takashiro; Einaga, Yasuaki.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 60, No. 12, 12.2004, p. m640-m642.

Research output: Contribution to journal › Article › peer-review

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title = "Bis[(R)-3,5-dichloro-N-(1-phenylethyl)salicylideneaminato-k 2N,O]-copper(ll) and bis[(R)-3-ethoxy-N-(1-phenylethyl) salicylideneaminato-K2N,O]copper(ll)",

abstract = "The crystal structure of bis[(R)-3,5-dichloro-N-(1-phenyl-ethyl) salicylideneaminato- κ2N, O]-copper(II) and bis[(R)-3-ethoxy-N-(1-phenylethyl)salicylideneaminato-κ2N, O] copper(II) was investigated. The complexes adopt a compressed tetrahedral trans-[CuN2O2] coordination geometry. The complexes also differ from one another with respect to the 1-phenylethylamine moieties and the direction of the benzene rings. The structural change was found to be irreversible for both the complexes, though there are no intermolecular hydrogen bonds in the crystals.",

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AU - Akitsu, Takashiro

AU - Einaga, Yasuaki

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N2 - The crystal structure of bis[(R)-3,5-dichloro-N-(1-phenyl-ethyl) salicylideneaminato- κ2N, O]-copper(II) and bis[(R)-3-ethoxy-N-(1-phenylethyl)salicylideneaminato-κ2N, O] copper(II) was investigated. The complexes adopt a compressed tetrahedral trans-[CuN2O2] coordination geometry. The complexes also differ from one another with respect to the 1-phenylethylamine moieties and the direction of the benzene rings. The structural change was found to be irreversible for both the complexes, though there are no intermolecular hydrogen bonds in the crystals.

AB - The crystal structure of bis[(R)-3,5-dichloro-N-(1-phenyl-ethyl) salicylideneaminato- κ2N, O]-copper(II) and bis[(R)-3-ethoxy-N-(1-phenylethyl)salicylideneaminato-κ2N, O] copper(II) was investigated. The complexes adopt a compressed tetrahedral trans-[CuN2O2] coordination geometry. The complexes also differ from one another with respect to the 1-phenylethylamine moieties and the direction of the benzene rings. The structural change was found to be irreversible for both the complexes, though there are no intermolecular hydrogen bonds in the crystals.

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Bis[(R)-3,5-dichloro-N-(1-phenylethyl)salicylideneaminato-k ²N,O]-copper(ll) and bis[(R)-3-ethoxy-N-(1-phenylethyl) salicylideneaminato-K²N,O]copper(ll)

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