Bis[(R)-3,5-dichloro-N-(1-phenylethyl)salicylideneaminato-k 2N,O]-copper(ll) and bis[(R)-3-ethoxy-N-(1-phenylethyl) salicylideneaminato-K2N,O]copper(ll)

Takashiro Akitsu, Yasuaki Einaga

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The crystal structure of bis[(R)-3,5-dichloro-N-(1-phenyl-ethyl) salicylideneaminato- κ2N, O]-copper(II) and bis[(R)-3-ethoxy-N-(1-phenylethyl)salicylideneaminato-κ2N, O] copper(II) was investigated. The complexes adopt a compressed tetrahedral trans-[CuN2O2] coordination geometry. The complexes also differ from one another with respect to the 1-phenylethylamine moieties and the direction of the benzene rings. The structural change was found to be irreversible for both the complexes, though there are no intermolecular hydrogen bonds in the crystals.

Original languageEnglish
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume60
Issue number12
DOIs
Publication statusPublished - 2004 Dec

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Copper
Phenethylamines
copper
Benzene
Hydrogen
Hydrogen bonds
Crystal structure
benzene
hydrogen bonds
Crystals
crystal structure
Geometry
rings
geometry
crystals
Direction compound

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

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title = "Bis[(R)-3,5-dichloro-N-(1-phenylethyl)salicylideneaminato-k 2N,O]-copper(ll) and bis[(R)-3-ethoxy-N-(1-phenylethyl) salicylideneaminato-K2N,O]copper(ll)",
abstract = "The crystal structure of bis[(R)-3,5-dichloro-N-(1-phenyl-ethyl) salicylideneaminato- κ2N, O]-copper(II) and bis[(R)-3-ethoxy-N-(1-phenylethyl)salicylideneaminato-κ2N, O] copper(II) was investigated. The complexes adopt a compressed tetrahedral trans-[CuN2O2] coordination geometry. The complexes also differ from one another with respect to the 1-phenylethylamine moieties and the direction of the benzene rings. The structural change was found to be irreversible for both the complexes, though there are no intermolecular hydrogen bonds in the crystals.",
author = "Takashiro Akitsu and Yasuaki Einaga",
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language = "English",
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T1 - Bis[(R)-3,5-dichloro-N-(1-phenylethyl)salicylideneaminato-k 2N,O]-copper(ll) and bis[(R)-3-ethoxy-N-(1-phenylethyl) salicylideneaminato-K2N,O]copper(ll)

AU - Akitsu, Takashiro

AU - Einaga, Yasuaki

PY - 2004/12

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N2 - The crystal structure of bis[(R)-3,5-dichloro-N-(1-phenyl-ethyl) salicylideneaminato- κ2N, O]-copper(II) and bis[(R)-3-ethoxy-N-(1-phenylethyl)salicylideneaminato-κ2N, O] copper(II) was investigated. The complexes adopt a compressed tetrahedral trans-[CuN2O2] coordination geometry. The complexes also differ from one another with respect to the 1-phenylethylamine moieties and the direction of the benzene rings. The structural change was found to be irreversible for both the complexes, though there are no intermolecular hydrogen bonds in the crystals.

AB - The crystal structure of bis[(R)-3,5-dichloro-N-(1-phenyl-ethyl) salicylideneaminato- κ2N, O]-copper(II) and bis[(R)-3-ethoxy-N-(1-phenylethyl)salicylideneaminato-κ2N, O] copper(II) was investigated. The complexes adopt a compressed tetrahedral trans-[CuN2O2] coordination geometry. The complexes also differ from one another with respect to the 1-phenylethylamine moieties and the direction of the benzene rings. The structural change was found to be irreversible for both the complexes, though there are no intermolecular hydrogen bonds in the crystals.

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