C-C bond formation with carbon dioxide promoted by a silver catalyst

Satoshi Kikuchi, Kohei Sekine, Tomonobu Ishida, Tohru Yamada

Research output: Contribution to journalArticle

68 Citations (Scopus)

Abstract

A catalytic amount of silver benzoate with 7-methyl-1,5,7-triazabicyclo[4. 4.0]dec-5-ene (MTBD) was an effective catalytic system for the reaction of carbon dioxide with various ketones containing an alkyne group at an appropriate position (see scheme). These reactions afforded the corresponding γ-lactone derivatives in good to high yields under mild conditions.

Original languageEnglish
Pages (from-to)6989-6992
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number28
DOIs
Publication statusPublished - 2012 Jul 9

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Alkynes
Benzoates
Lactones
Ketones
Silver
Carbon Dioxide
Carbon dioxide
Derivatives
Catalysts

Keywords

  • C-C bond formation
  • carbon dioxide
  • homogeneous catalysis
  • silver
  • synthetic methods

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

C-C bond formation with carbon dioxide promoted by a silver catalyst. / Kikuchi, Satoshi; Sekine, Kohei; Ishida, Tomonobu; Yamada, Tohru.

In: Angewandte Chemie - International Edition, Vol. 51, No. 28, 09.07.2012, p. 6989-6992.

Research output: Contribution to journalArticle

Kikuchi, Satoshi ; Sekine, Kohei ; Ishida, Tomonobu ; Yamada, Tohru. / C-C bond formation with carbon dioxide promoted by a silver catalyst. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 28. pp. 6989-6992.
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