Capillary electrophoretic determination of inorganic and organic anions using 2,6-pyridinedicarboxylic acid: Effect of electrolyte's complexing ability

Tomoyoshi Soga, Gordon A. Ross

Research output: Contribution to journalArticle

108 Citations (Scopus)

Abstract

A capillary zone electrophoresis method was developed with indirect UV detection for the analysis of inorganic and organic anions using a background electrolyte (BGE), 2,6-pyridinedicarboxylic acid (PDC). The parameters which influence the separation of these anions, such as electrolyte pH, concentration of PDC and applied voltage, were investigated. Three inorganic anions and nine organic acids were determined simultaneously in less than 7 min. The R.S.D. (n=6) values of the method were around 0.1% for migration time and better than 2.6% for peak area. This method is rapid, sensitive and quantitative and could be readily applied to the analysis of inorganic and organic anions in beer. In the present paper, the effect of the complexing ability of the BGE on the analysis of organic acids is also discussed.

Original languageEnglish
Pages (from-to)223-230
Number of pages8
JournalJournal of Chromatography A
Volume767
Issue number1-2
DOIs
Publication statusPublished - 1997 Apr 11
Externally publishedYes

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Electrolytes
Anions
Organic acids
Acids
Beer
Capillary Electrophoresis
Electrophoresis
2,6-pyridinedicarboxylic acid
Electric potential

Keywords

  • 2,6-Pyridinedicarboxylic acid
  • Anions
  • Background electrolyte composition

ASJC Scopus subject areas

  • Analytical Chemistry

Cite this

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abstract = "A capillary zone electrophoresis method was developed with indirect UV detection for the analysis of inorganic and organic anions using a background electrolyte (BGE), 2,6-pyridinedicarboxylic acid (PDC). The parameters which influence the separation of these anions, such as electrolyte pH, concentration of PDC and applied voltage, were investigated. Three inorganic anions and nine organic acids were determined simultaneously in less than 7 min. The R.S.D. (n=6) values of the method were around 0.1{\%} for migration time and better than 2.6{\%} for peak area. This method is rapid, sensitive and quantitative and could be readily applied to the analysis of inorganic and organic anions in beer. In the present paper, the effect of the complexing ability of the BGE on the analysis of organic acids is also discussed.",
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AU - Ross, Gordon A.

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N2 - A capillary zone electrophoresis method was developed with indirect UV detection for the analysis of inorganic and organic anions using a background electrolyte (BGE), 2,6-pyridinedicarboxylic acid (PDC). The parameters which influence the separation of these anions, such as electrolyte pH, concentration of PDC and applied voltage, were investigated. Three inorganic anions and nine organic acids were determined simultaneously in less than 7 min. The R.S.D. (n=6) values of the method were around 0.1% for migration time and better than 2.6% for peak area. This method is rapid, sensitive and quantitative and could be readily applied to the analysis of inorganic and organic anions in beer. In the present paper, the effect of the complexing ability of the BGE on the analysis of organic acids is also discussed.

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