Carbon–Carbon Bond Formation via Catalytically Generated Aminocarbene Complexes: Rhodium-Catalyzed Hydroaminative Cyclization of Enynes with Secondary Amines

Shotaro Takano, Ryosuke Shiomi, Yoshihiko Morimoto, Takuya Kochi, Fumitoshi Kakiuchi

Research output: Contribution to journalArticle

Abstract

We report a hydroaminative cyclization of enynes using phosphine-quinolinolato rhodium catalysts. The hydroaminative cyclization of 2-vinylphenylacetylene derivatives with secondary amines gives 2-aminoindenes in good yields. The reaction is considered to proceed through carbon–carbon bond formation on a catalytically generated aminocarbene ligand.

Original languageEnglish
Pages (from-to)11754-11757
Number of pages4
JournalAngewandte Chemie - International Edition
Volume59
Issue number29
DOIs
Publication statusPublished - 2020 Jul 13

Keywords

  • aminocarbene complexes
  • enynes
  • hydroaminative cyclization
  • rhodium
  • secondary amines

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Fingerprint Dive into the research topics of 'Carbon–Carbon Bond Formation via Catalytically Generated Aminocarbene Complexes: Rhodium-Catalyzed Hydroaminative Cyclization of Enynes with Secondary Amines'. Together they form a unique fingerprint.

  • Cite this