@article{1f4aad5bbdd4438587b9c758c1c05ec8,
title = "Carbon–Carbon Bond Formation via Catalytically Generated Aminocarbene Complexes: Rhodium-Catalyzed Hydroaminative Cyclization of Enynes with Secondary Amines",
abstract = "We report a hydroaminative cyclization of enynes using phosphine-quinolinolato rhodium catalysts. The hydroaminative cyclization of 2-vinylphenylacetylene derivatives with secondary amines gives 2-aminoindenes in good yields. The reaction is considered to proceed through carbon–carbon bond formation on a catalytically generated aminocarbene ligand.",
keywords = "aminocarbene complexes, enynes, hydroaminative cyclization, rhodium, secondary amines",
author = "Shotaro Takano and Ryosuke Shiomi and Yoshihiko Morimoto and Takuya Kochi and Fumitoshi Kakiuchi",
note = "Funding Information: F.K. thanks to financial support, in part, by the Promotion of Science (JSPS) KAKENHI Grant Numbers JP17K19126, JP16H04150, and JP15H05839 (Middle Molecular Strategy). T.K. is also grateful for financial support provided by JSPS KAKENHI Grant Number JP18H04271 (Precisely Designed Catalysts with Customized Scaffolding) and the Asahi Glass Foundation. S.T. is also grateful for support by the Research Grant of Keio Leading-edge Laboratory of Science & Technology. Funding Information: F.K. thanks to financial support, in part, by the Promotion of Science (JSPS) KAKENHI Grant Numbers JP17K19126, JP16H04150, and JP15H05839 (Middle Molecular Strategy). T.K. is also grateful for financial support provided by JSPS KAKENHI Grant Number JP18H04271 (Precisely Designed Catalysts with Customized Scaffolding) and the Asahi Glass Foundation. S.T. is also grateful for support by the Research Grant of Keio Leading‐edge Laboratory of Science & Technology. Publisher Copyright: {\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2020",
month = jul,
day = "13",
doi = "10.1002/anie.202002710",
language = "English",
volume = "59",
pages = "11754--11757",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "29",
}