Catalytic asymmetric oxidation of N-sulfonyl imines with hydrogen peroxide-trichloroacetonitrile system

Daisuke Uraguchi; Ryosuke Tsutsumi; Takashi Ooi

doi:10.1021/ja403491j

Catalytic asymmetric oxidation of N-sulfonyl imines with hydrogen peroxide-trichloroacetonitrile system

Daisuke Uraguchi, Ryosuke Tsutsumi, Takashi Ooi

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

An efficient and highly enantioselective Payne-type oxidation of N-sulfonyl imines is developed. The reaction exhibits broad substrate generality and unique chemoselectivity based on the combined use of hydrogen peroxide and trichloroacetonitrile under the catalysis of P-spiro chiral triaminoiminophosphorane.

Original language	English
Pages (from-to)	8161-8164
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	22
DOIs	https://doi.org/10.1021/ja403491j
Publication status	Published - 2013 Jun 5
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja403491j

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abstract = "An efficient and highly enantioselective Payne-type oxidation of N-sulfonyl imines is developed. The reaction exhibits broad substrate generality and unique chemoselectivity based on the combined use of hydrogen peroxide and trichloroacetonitrile under the catalysis of P-spiro chiral triaminoiminophosphorane.",

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AU - Tsutsumi, Ryosuke

AU - Ooi, Takashi

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AB - An efficient and highly enantioselective Payne-type oxidation of N-sulfonyl imines is developed. The reaction exhibits broad substrate generality and unique chemoselectivity based on the combined use of hydrogen peroxide and trichloroacetonitrile under the catalysis of P-spiro chiral triaminoiminophosphorane.

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Catalytic asymmetric oxidation of N-sulfonyl imines with hydrogen peroxide-trichloroacetonitrile system

Abstract

ASJC Scopus subject areas

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