Catalytic asymmetric oxidation of N-sulfonyl imines with hydrogen peroxide-trichloroacetonitrile system

Daisuke Uraguchi, Ryosuke Tsutsumi, Takashi Ooi

Research output: Contribution to journalArticlepeer-review

52 Citations (Scopus)

Abstract

An efficient and highly enantioselective Payne-type oxidation of N-sulfonyl imines is developed. The reaction exhibits broad substrate generality and unique chemoselectivity based on the combined use of hydrogen peroxide and trichloroacetonitrile under the catalysis of P-spiro chiral triaminoiminophosphorane.

Original languageEnglish
Pages (from-to)8161-8164
Number of pages4
JournalJournal of the American Chemical Society
Volume135
Issue number22
DOIs
Publication statusPublished - 2013 Jun 5
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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