Catalytic atropo -enantioselective preparation of axially chiral biaryl compounds

Tomoko Ashizawa, Tohru Yamada

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The atriopo-enantioselective ring-opening of biaryl lactones with methanol was catalyzed by an optically active AgBF 4-phosphine complex to afford axially chiral biaryl compounds. The addition of triisobutylamine provided a dramatic rate acceleration in the reaction. Various types of axially chiral biaryl compounds were obtained with high enantioselectivity.

Original languageEnglish
Pages (from-to)246-247
Number of pages2
JournalChemistry Letters
Volume38
Issue number3
DOIs
Publication statusPublished - 2009

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phosphine
Enantioselectivity
Lactones
Methanol

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Catalytic atropo -enantioselective preparation of axially chiral biaryl compounds. / Ashizawa, Tomoko; Yamada, Tohru.

In: Chemistry Letters, Vol. 38, No. 3, 2009, p. 246-247.

Research output: Contribution to journalArticle

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