Catalytic C-H/olefin coupling

Fumitoshi Kakiuchi, Shinji Murai

Research output: Contribution to journalArticle

911 Citations (Scopus)

Abstract

The cleavage and addition of ortho C-H bonds in various aromatic compounds such as ketones, esters, imines, imidates, nitrile, and aldehydes to olefins and acetlylenes can be achieved catalytically with the aid of ruthenium catalysts. The reaction is generally highly efficient and useful in synthetic methods. The coordination to the metal center by a heteroatom in directing groups such as carbonyl and imino groups is the key. The reductive elimination to form a C-C bond is the rate-determining step.

Original languageEnglish
Pages (from-to)826-834
Number of pages9
JournalAccounts of Chemical Research
Volume35
Issue number10
DOIs
Publication statusPublished - 2002 Oct
Externally publishedYes

Fingerprint

Imidoesters
Nitriles
Imines
Ruthenium
Aromatic compounds
Alkenes
Ketones
Aldehydes
Esters
Metals
Catalysts

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Catalytic C-H/olefin coupling. / Kakiuchi, Fumitoshi; Murai, Shinji.

In: Accounts of Chemical Research, Vol. 35, No. 10, 10.2002, p. 826-834.

Research output: Contribution to journalArticle

Kakiuchi, Fumitoshi ; Murai, Shinji. / Catalytic C-H/olefin coupling. In: Accounts of Chemical Research. 2002 ; Vol. 35, No. 10. pp. 826-834.
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