Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination

Naoya Kumagai; Shigeki Matsunaga; Masakatsu Shibasaki

doi:10.1039/b504519c

Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination

Naoya Kumagai, Shigeki Matsunaga, Masakatsu Shibasaki

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The cooperative catalysis of CpRu(PPh₃)₂(CH ₃CN)PF₆ (1b) and DBU enables chemoselective nucleophilic activation of acetonitrile in the presence of base-sensitive aldehydes 2 to afford corresponding β-hydroxynitriles 3 in good yield.

Original language	English
Pages (from-to)	3600-3602
Number of pages	3
Journal	Chemical Communications
Issue number	28
DOIs	https://doi.org/10.1039/b504519c
Publication status	Published - 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b504519c

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title = "Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination",

abstract = "The cooperative catalysis of CpRu(PPh3)2(CH 3CN)PF6 (1b) and DBU enables chemoselective nucleophilic activation of acetonitrile in the presence of base-sensitive aldehydes 2 to afford corresponding β-hydroxynitriles 3 in good yield.",

author = "Naoya Kumagai and Shigeki Matsunaga and Masakatsu Shibasaki",

year = "2005",

doi = "10.1039/b504519c",

language = "English",

pages = "3600--3602",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "28",

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TY - JOUR

T1 - Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination

AU - Kumagai, Naoya

AU - Matsunaga, Shigeki

AU - Shibasaki, Masakatsu

PY - 2005

Y1 - 2005

N2 - The cooperative catalysis of CpRu(PPh3)2(CH 3CN)PF6 (1b) and DBU enables chemoselective nucleophilic activation of acetonitrile in the presence of base-sensitive aldehydes 2 to afford corresponding β-hydroxynitriles 3 in good yield.

AB - The cooperative catalysis of CpRu(PPh3)2(CH 3CN)PF6 (1b) and DBU enables chemoselective nucleophilic activation of acetonitrile in the presence of base-sensitive aldehydes 2 to afford corresponding β-hydroxynitriles 3 in good yield.

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UR - http://www.scopus.com/inward/citedby.url?scp=24044486627&partnerID=8YFLogxK

U2 - 10.1039/b504519c

DO - 10.1039/b504519c

M3 - Article

C2 - 16010337

AN - SCOPUS:24044486627

SN - 1359-7345

SP - 3600

EP - 3602

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination

Abstract

ASJC Scopus subject areas

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