Catalytic dimerization of acrylonitrile

Kohichi Kashiwagi; Ryoji Sugise; Toshihiro Shimakawa; Tunao Matuura; Masashi Shirai; Fumitoshi Kakiuchi; Shinji Murai

doi:10.1021/om970263a

Catalytic dimerization of acrylonitrile

Kohichi Kashiwagi, Ryoji Sugise, Toshihiro Shimakawa, Tunao Matuura, Masashi Shirai, Fumitoshi Kakiuchi, Shinji Murai

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

A new catalytic system using the combination RuCl₂(DMSO)₄/CH₃CH ₃COONa/DMSO/carboxylic acid which enables selective dimerization of acrylonitrile to linear dimers without formation of propionitrile as a byproduct has been developed on the basis of a new working hypothesis of the desirable reaction mechanism involving protonolysis of a C-Ru bond in the intermediate.

Original language	English
Pages (from-to)	2233-2235
Number of pages	3
Journal	Organometallics
Volume	16
Issue number	11
DOIs	https://doi.org/10.1021/om970263a
Publication status	Published - 1997 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om970263a

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abstract = "A new catalytic system using the combination RuCl2(DMSO)4/CH3CH 3COONa/DMSO/carboxylic acid which enables selective dimerization of acrylonitrile to linear dimers without formation of propionitrile as a byproduct has been developed on the basis of a new working hypothesis of the desirable reaction mechanism involving protonolysis of a C-Ru bond in the intermediate.",

author = "Kohichi Kashiwagi and Ryoji Sugise and Toshihiro Shimakawa and Tunao Matuura and Masashi Shirai and Fumitoshi Kakiuchi and Shinji Murai",

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T1 - Catalytic dimerization of acrylonitrile

AU - Kashiwagi, Kohichi

AU - Sugise, Ryoji

AU - Shimakawa, Toshihiro

AU - Matuura, Tunao

AU - Shirai, Masashi

AU - Kakiuchi, Fumitoshi

AU - Murai, Shinji

PY - 1997/1/1

Y1 - 1997/1/1

N2 - A new catalytic system using the combination RuCl2(DMSO)4/CH3CH 3COONa/DMSO/carboxylic acid which enables selective dimerization of acrylonitrile to linear dimers without formation of propionitrile as a byproduct has been developed on the basis of a new working hypothesis of the desirable reaction mechanism involving protonolysis of a C-Ru bond in the intermediate.

AB - A new catalytic system using the combination RuCl2(DMSO)4/CH3CH 3COONa/DMSO/carboxylic acid which enables selective dimerization of acrylonitrile to linear dimers without formation of propionitrile as a byproduct has been developed on the basis of a new working hypothesis of the desirable reaction mechanism involving protonolysis of a C-Ru bond in the intermediate.

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Catalytic dimerization of acrylonitrile

Abstract

ASJC Scopus subject areas

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