Catalytic dimerization of acrylonitrile

Kohichi Kashiwagi, Ryoji Sugise, Toshihiro Shimakawa, Tunao Matuura, Masashi Shirai, Fumitoshi Kakiuchi, Shinji Murai

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

A new catalytic system using the combination RuCl2(DMSO)4/CH3CH 3COONa/DMSO/carboxylic acid which enables selective dimerization of acrylonitrile to linear dimers without formation of propionitrile as a byproduct has been developed on the basis of a new working hypothesis of the desirable reaction mechanism involving protonolysis of a C-Ru bond in the intermediate.

Original languageEnglish
Pages (from-to)2233-2235
Number of pages3
JournalOrganometallics
Volume16
Issue number11
Publication statusPublished - 1997
Externally publishedYes

Fingerprint

Acrylonitrile
Dimerization
acrylonitriles
dimerization
Carboxylic Acids
Dimethyl Sulfoxide
carboxylic acids
Dimers
Byproducts
dimers
propionitrile
dichlorotetrakis(dimethyl sulfoxide)ruthenium II

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Kashiwagi, K., Sugise, R., Shimakawa, T., Matuura, T., Shirai, M., Kakiuchi, F., & Murai, S. (1997). Catalytic dimerization of acrylonitrile. Organometallics, 16(11), 2233-2235.

Catalytic dimerization of acrylonitrile. / Kashiwagi, Kohichi; Sugise, Ryoji; Shimakawa, Toshihiro; Matuura, Tunao; Shirai, Masashi; Kakiuchi, Fumitoshi; Murai, Shinji.

In: Organometallics, Vol. 16, No. 11, 1997, p. 2233-2235.

Research output: Contribution to journalArticle

Kashiwagi, K, Sugise, R, Shimakawa, T, Matuura, T, Shirai, M, Kakiuchi, F & Murai, S 1997, 'Catalytic dimerization of acrylonitrile', Organometallics, vol. 16, no. 11, pp. 2233-2235.
Kashiwagi K, Sugise R, Shimakawa T, Matuura T, Shirai M, Kakiuchi F et al. Catalytic dimerization of acrylonitrile. Organometallics. 1997;16(11):2233-2235.
Kashiwagi, Kohichi ; Sugise, Ryoji ; Shimakawa, Toshihiro ; Matuura, Tunao ; Shirai, Masashi ; Kakiuchi, Fumitoshi ; Murai, Shinji. / Catalytic dimerization of acrylonitrile. In: Organometallics. 1997 ; Vol. 16, No. 11. pp. 2233-2235.
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