Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current

Hiroko Aiso, Takuya Kochi, Hitoshi Mutsutani, Takamasa Tanabe, Shigeru Nishiyama, Fumitoshi Kakiuchi

Research output: Contribution to journalArticle

72 Citations (Scopus)

Abstract

Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.

Original languageEnglish
Pages (from-to)7718-7724
Number of pages7
JournalJournal of Organic Chemistry
Volume77
Issue number17
DOIs
Publication statusPublished - 2012 Sep 7

ASJC Scopus subject areas

  • Organic Chemistry

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