Catalytic enantioselective epoxidation with arabinose-derived uloses containing tunable steric sensors

Tony K.M. Shing; Gulice Y.C. Leung; Kwan W. Yeung

doi:10.1016/j.tetlet.2003.09.226

Catalytic enantioselective epoxidation with arabinose-derived uloses containing tunable steric sensors

Tony K.M. Shing, Gulice Y.C. Leung, Kwan W. Yeung

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Readily available arabinose-derived 4-uloses, containing a tunable butane-2,3-diacetal as the steric sensor, displayed increasing enantioselectivity (up to 93% ee) with the size of the acetal alkyl group in catalytic asymmetric epoxidation of trans-disubstituted and trisubstituted alkenes.

Original language	English
Pages (from-to)	9225-9228
Number of pages	4
Journal	Tetrahedron Letters
Volume	44
Issue number	51
DOIs	https://doi.org/10.1016/j.tetlet.2003.09.226
Publication status	Published - 2003 Dec 15

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2003.09.226

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abstract = "Readily available arabinose-derived 4-uloses, containing a tunable butane-2,3-diacetal as the steric sensor, displayed increasing enantioselectivity (up to 93% ee) with the size of the acetal alkyl group in catalytic asymmetric epoxidation of trans-disubstituted and trisubstituted alkenes.",

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Catalytic enantioselective epoxidation with arabinose-derived uloses containing tunable steric sensors

Abstract

ASJC Scopus subject areas

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