Abstract
The development of catalytic reactions involving carbon-hydrogen bond cleavage is currently one of the most attractive research subjects in organic and organometallic chemistry. About 40 years have past since the pioneering report of the cleavage of C-H bonds with transition metal complexes. Since that time, a vast number of studies of the cleavage of C-H bonds, using stoichiometric amounts of transition metal complexes has appeared. In the last decade, a variety of catalytic reactions involving C-H bond cleavage has been reported. In this review we briefly survey the results of these research activities with respect to the catalytic use of unreactive C-H bonds in organic synthesis.
| Original language | English |
|---|---|
| Pages (from-to) | 1077-1101 |
| Number of pages | 25 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 345 |
| Issue number | 9-10 |
| DOIs | |
| Publication status | Published - 2003 Sep |
Keywords
- Alkenylation
- Alkylation
- Borylation
- C-C bond formation
- C-H activation
- Carbonylation
- Silylation
- Transition metal catalysts
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
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Cite this
Kakiuchi, F., & Chatani, N. (2003). Catalytic Methods for C-H Bond Functionalization: Application in Organic Synthesis. Advanced Synthesis and Catalysis, 345(9-10), 1077-1101. https://doi.org/10.1002/adsc.200303094