Catalytic oxidation-reduction hydration of olefin with molecular oxygen in the presence of bis(1,3-diketonato)cobalt(II) complexes

K. Kato, Tohru Yamada, T. Takai, S. Inoki, S. Isayama

Research output: Contribution to journalArticle

69 Citations (Scopus)

Abstract

In the presence of a bis(1,3-diketonato)cobalt(II) complex, various olefins are converted to the corresponding hydrated products according to the Markownikov rule on treatment with molecular oxygen in secondary alcohol (''oxidation-reduction hydration''). Removal of water formed during the hydration reaction, especially by azeotropic method, is remarkably effective to improve yields of the hydrated products based on the cobalt(II) catalyst as bis(trifluoroacetylacetonato)cobalt(II) (Co(tfa)2) or bis(2-ethoxycarbonyl-3-oxobutanalato)-cobalt(II) (Co(ecbo)2).

Original languageEnglish
Pages (from-to)179-186
Number of pages8
JournalBulletin of the Chemical Society of Japan
Volume63
Issue number1
DOIs
Publication statusPublished - 1990
Externally publishedYes

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Molecular oxygen
Catalytic oxidation
Alkenes
Cobalt
Hydration
Alcohols
Catalysts
Oxidation-Reduction
Water

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Catalytic oxidation-reduction hydration of olefin with molecular oxygen in the presence of bis(1,3-diketonato)cobalt(II) complexes. / Kato, K.; Yamada, Tohru; Takai, T.; Inoki, S.; Isayama, S.

In: Bulletin of the Chemical Society of Japan, Vol. 63, No. 1, 1990, p. 179-186.

Research output: Contribution to journalArticle

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AU - Inoki, S.

AU - Isayama, S.

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