Catalytic oxidation-reduction hydration of olefin with molecular oxygen in the presence of bis(1,3-diketonato)cobalt(II) complexes

K. Kato, T. Yamada, T. Takai, S. Inoki, S. Isayama

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Abstract

In the presence of a bis(1,3-diketonato)cobalt(II) complex, various olefins are converted to the corresponding hydrated products according to the Markownikov rule on treatment with molecular oxygen in secondary alcohol (''oxidation-reduction hydration''). Removal of water formed during the hydration reaction, especially by azeotropic method, is remarkably effective to improve yields of the hydrated products based on the cobalt(II) catalyst as bis(trifluoroacetylacetonato)cobalt(II) (Co(tfa)2) or bis(2-ethoxycarbonyl-3-oxobutanalato)-cobalt(II) (Co(ecbo)2).

Original languageEnglish
Pages (from-to)179-186
Number of pages8
JournalBulletin of the Chemical Society of Japan
Volume63
Issue number1
DOIs
Publication statusPublished - 1990 Jun 22

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ASJC Scopus subject areas

  • Chemistry(all)

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