Catalytic reactions enhanced under microwave-induced local thermal non-equilibrium in a core-shell, carbon-filled zeolite@zeolite

Dai Mochizuki, Ryo Sasaki, Masato M. Maitani, Masaki Okamoto, Eiichi Suzuki, Yuji Wada

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A core-shell, carbon-filled zeolite@zeolite was created through the epitaxial growth of shell zeolite on a core zeolite filled with carbon. The catalytic dehydrations of alcohols on the core-shell structure were enhanced under microwave irradiation by comparison with conventional heating using an oil bath at the same solution temperatures; however, the dehydrations on the sole core zeolite were not enhanced under microwave irradiation, which indicated the presence of a higher temperature area in the shell near the border with the core. The core-shell structure exhibited thermal non-equilibrium with microwave irradiation because of the extremely different dielectric losses of the core and the shell; that is, the carbon in the core generated much heat from microwaves, but the shell did not.

Original languageEnglish
Pages (from-to)1-9
Number of pages9
JournalJournal of Catalysis
Volume323
DOIs
Publication statusPublished - 2015 Mar 1
Externally publishedYes

Fingerprint

Zeolites
Microwave irradiation
Carbon
Microwaves
Dehydration
microwaves
carbon
Dielectric losses
Epitaxial growth
Alcohols
dehydration
irradiation
Heating
Temperature
Oils
Hot Temperature
borders
dielectric loss
baths
alcohols

Keywords

  • Core-shell
  • Dehydration
  • Microwave
  • Zeolite

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

Catalytic reactions enhanced under microwave-induced local thermal non-equilibrium in a core-shell, carbon-filled zeolite@zeolite. / Mochizuki, Dai; Sasaki, Ryo; Maitani, Masato M.; Okamoto, Masaki; Suzuki, Eiichi; Wada, Yuji.

In: Journal of Catalysis, Vol. 323, 01.03.2015, p. 1-9.

Research output: Contribution to journalArticle

Mochizuki, Dai ; Sasaki, Ryo ; Maitani, Masato M. ; Okamoto, Masaki ; Suzuki, Eiichi ; Wada, Yuji. / Catalytic reactions enhanced under microwave-induced local thermal non-equilibrium in a core-shell, carbon-filled zeolite@zeolite. In: Journal of Catalysis. 2015 ; Vol. 323. pp. 1-9.
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