Catalytic Reactions of Terminal Alkynes Using Rhodium(I) Complexes Bearing 8-Quinolinolate Ligands

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

8-Quinolinolate is a monoanionic, hard, strongly σ-donating ligand that can form strong chelates with various metals. However, studies of the catalytic activities of soft transition metal complexes such as greater than second row, low-valent, late-transition metals having 8-quinolinolate ligands had not been well explored until recently. In recent years, several research groups including our own have studied and developed various reactions of terminal alkynes using rhodium(I) catalysts containing an 8-quinolinolate ligand. In this Perspective, we surveyed the transformations of terminal alkynes using 8-quinolinolato rhodium(I) catalyst such as additions of alcohols, amines, and thiols as well as polymerization, trimerization, dimerization, and alkyne/alkene [2 + 2] cycloaddition. Mechanistic studies based on theoretical calculations of hydroalkoxylation of alkynes and alkyne/alkene [2 + 2] cycloaddition reactions have also been described.

Original languageEnglish
Pages (from-to)6127-6137
Number of pages11
JournalACS Catalysis
Volume8
Issue number7
DOIs
Publication statusPublished - 2018 Jul 6

Keywords

  • 8-quinolinolate ligands
  • alkyne/alkene coupling
  • alkyne/alkyne coupling
  • anti-Markovnikov addition
  • hydroalkoxylation
  • hydroamination
  • hydrothiolation
  • terminal alkynes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Fingerprint

Dive into the research topics of 'Catalytic Reactions of Terminal Alkynes Using Rhodium(I) Complexes Bearing 8-Quinolinolate Ligands'. Together they form a unique fingerprint.

Cite this