Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O: O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]

Yoshiyuki Kani, Masanobu Tsuchimoto, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The two title compounds, [Cu3(C6H11O2)6(C 7H9N)2]n, (I), and [Cu2(C5H9O2)4(C 7H9N)2], (II), have chain and finite-molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6-dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one-dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6-dimethylpyridine at the apical position.

Original languageEnglish
Pages (from-to)923-925
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number8
Publication statusPublished - 2000

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Copper
inversions
copper
Molecular Structure
Molecular structure
carboxylates
molecular structure
Ions
Atoms
Geometry
geometry
atoms
ions
2,6-lutidine

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

@article{c125f0e000944f9794dfbef53688820b,
title = "Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O: O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]",
abstract = "The two title compounds, [Cu3(C6H11O2)6(C 7H9N)2]n, (I), and [Cu2(C5H9O2)4(C 7H9N)2], (II), have chain and finite-molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6-dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one-dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6-dimethylpyridine at the apical position.",
author = "Yoshiyuki Kani and Masanobu Tsuchimoto and Shigeru Ohba and Hideaki Matsushima and Tadashi Tokii",
year = "2000",
language = "English",
volume = "56",
pages = "923--925",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "8",

}

TY - JOUR

T1 - Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O

T2 - O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]

AU - Kani, Yoshiyuki

AU - Tsuchimoto, Masanobu

AU - Ohba, Shigeru

AU - Matsushima, Hideaki

AU - Tokii, Tadashi

PY - 2000

Y1 - 2000

N2 - The two title compounds, [Cu3(C6H11O2)6(C 7H9N)2]n, (I), and [Cu2(C5H9O2)4(C 7H9N)2], (II), have chain and finite-molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6-dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one-dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6-dimethylpyridine at the apical position.

AB - The two title compounds, [Cu3(C6H11O2)6(C 7H9N)2]n, (I), and [Cu2(C5H9O2)4(C 7H9N)2], (II), have chain and finite-molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6-dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one-dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6-dimethylpyridine at the apical position.

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M3 - Article

AN - SCOPUS:0034238624

VL - 56

SP - 923

EP - 925

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 8

ER -