Chain-walking cycloisomerization of 1,n-dienes catalyzed by pyridine-oxazoline palladium catalysts and its application to asymmetric synthesis

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Abstract

Palladium catalysts possessing pyridineoxazoline ligands were found to catalyze the chain-walking cycloisomerization of 1,n-dienes to form five-membered rings and were particularly effective for the reaction of 1,14-dienes. Asymmetric synthesis of cyclopentane derivatives was also achieved for the reaction of 1,n-dienes using chiral pyridineoxazoline ligands.

Original languageEnglish
Pages (from-to)297-299
Number of pages3
JournalChemistry Letters
Volume45
Issue number3
DOIs
Publication statusPublished - 2016

Keywords

  • Asymmetric synthesis
  • Chain-walking cycloisomerization
  • Pyridine-oxazoline palladium catalyst

ASJC Scopus subject areas

  • Chemistry(all)

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