Characteristics of CeO2 nanocubes and related polyhedra prepared by using a liquid-liquid interface

Feng Dang, Kazumi Kato, Hiroaki Imai, Satoshi Wada, Hajime Haneda, Makoto Kuwabara

Research output: Contribution to journalArticle

70 Citations (Scopus)

Abstract

Monodispersed CeO2 nanocubes were prepared by using a liquid-liquid interface. The morphology of CeO2 nanocrystals from the aqueous phase changed from truncated octahedron to nanocube in the toluene phase at the water-toluene interface. The CeO2 nanocubes oriented to form large cubic particles at a low molar ratio of oleic acid (OLA)/Ce. The red-shift of the absorption edge and the high concentration of Ce3+ in the CeO2 structure was identified for the CeO2 nanocrystals. The high concentration of Ce3+ in the CeO2 structure was identified as one of the main reasons for the red-shift of the absorption edge of CeO2 nanocrystals.

Original languageEnglish
Pages (from-to)4537-4541
Number of pages5
JournalCrystal Growth and Design
Volume10
Issue number10
DOIs
Publication statusPublished - 2010 Oct 6

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liquid-liquid interfaces
polyhedrons
Nanocrystals
nanocrystals
Toluene
red shift
toluene
Liquids
oleic acid
Oleic acid
Oleic Acid
Water
water

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Characteristics of CeO2 nanocubes and related polyhedra prepared by using a liquid-liquid interface. / Dang, Feng; Kato, Kazumi; Imai, Hiroaki; Wada, Satoshi; Haneda, Hajime; Kuwabara, Makoto.

In: Crystal Growth and Design, Vol. 10, No. 10, 06.10.2010, p. 4537-4541.

Research output: Contribution to journalArticle

Dang, Feng ; Kato, Kazumi ; Imai, Hiroaki ; Wada, Satoshi ; Haneda, Hajime ; Kuwabara, Makoto. / Characteristics of CeO2 nanocubes and related polyhedra prepared by using a liquid-liquid interface. In: Crystal Growth and Design. 2010 ; Vol. 10, No. 10. pp. 4537-4541.
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